Th emajor fragmentation of the following molecule occurs through the Mclafferty rearrangement . which of the following is expected to be the base peak in the mass spectrum? I cleaved the compound on the bonds adjacent to the alpha and calculated the mass for the biggest fragment, which was m/z= 73. The answer is actually m/z = 86. Can someone give me a step by step on how to do this problem?
Th emajor fragmentation of the following molecule occurs through the Mclafferty rearrangement . which of the following is expected to be the base peak in the mass spectrum? I cleaved the compound on the bonds adjacent to the alpha and calculated the mass for the biggest fragment, which was m/z= 73. The answer is actually m/z = 86. Can someone give me a step by step on how to do this problem?
Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter3: Chemical Reactions
Section3.9: Classifying Reactions In Aqueous Solution
Problem 2.2ACP
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Th emajor fragmentation of the following molecule occurs through the Mclafferty rearrangement . which of the following is expected to be the base peak in the mass spectrum? I cleaved the compound on the bonds adjacent to the alpha and calculated the mass for the biggest fragment, which was m/z= 73. The answer is actually m/z = 86. Can someone give me a step by step on how to do this problem?
![1. Locate alpha
2. cleare adjacent to the alpha (2 possibilities
here)
CyHq = √5 +
3. rearrange to get
W
original molecule:
wy
H
(= 4 (12)
0= 16
H=9
-
73
m/2=73
of
&
vite stw
of:^](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F7588948d-a8a4-4b5d-b85a-786e24f76953%2Faa0fd760-e04f-4534-9d80-176e1d95d925%2Fi9a7d8w_processed.jpeg&w=3840&q=75)
Transcribed Image Text:1. Locate alpha
2. cleare adjacent to the alpha (2 possibilities
here)
CyHq = √5 +
3. rearrange to get
W
original molecule:
wy
H
(= 4 (12)
0= 16
H=9
-
73
m/2=73
of
&
vite stw
of:^
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