Tert-butyl alcohol reacts with aqueous hydrochloric acid to give tert-butyl chloride as shown below: (CH3);COH(aq) +H*(aq) + Cl'(aq) → (CH3)3CCI(ag) + H2O(1) For this reaction, rate = k[(CH3)3COH][H*]. With which mechanism is this rate law consistent? A) (CH3);COH(aq) + H*(aq) (fast) (slow) (slow) (fast) (fast) (slow) (fast) (fast) (slow) (fast) E) None of these mechanisms are consistent with the rate law provided. (CH3)3C(OH2)*(aq) (CH3):C(ОН2)(аg) + Cl(aq) > (CH3):CC(ag) + H0() в) (CH)3СОН(ад) > (СHз)3С(ag) + ОH-(aд) (CH):С"(ag) + CI (ag) > (CH):ССI(ag) H (aд) + ОН (aq) > H-О(1) C) (CH):СОН(aд) + Cl(aq) > (CH)3СCI'(aq) + ОН (aq) H'(aq) + ОН (аg) > H-О(1) D) (CH)3СОН(ад) + H'(ag) — (CH)3C(ОН)"(aд) (CH3)3C(OH2)*(aq) (CH3)3C(OH2)*(ag) → (CH3)3C*(ag) + H2O(1) (CH3)3C*(ag) + Cl(aq) → (CH3)3CCI(aq)
Tert-butyl alcohol reacts with aqueous hydrochloric acid to give tert-butyl chloride as shown below: (CH3);COH(aq) +H*(aq) + Cl'(aq) → (CH3)3CCI(ag) + H2O(1) For this reaction, rate = k[(CH3)3COH][H*]. With which mechanism is this rate law consistent? A) (CH3);COH(aq) + H*(aq) (fast) (slow) (slow) (fast) (fast) (slow) (fast) (fast) (slow) (fast) E) None of these mechanisms are consistent with the rate law provided. (CH3)3C(OH2)*(aq) (CH3):C(ОН2)(аg) + Cl(aq) > (CH3):CC(ag) + H0() в) (CH)3СОН(ад) > (СHз)3С(ag) + ОH-(aд) (CH):С"(ag) + CI (ag) > (CH):ССI(ag) H (aд) + ОН (aq) > H-О(1) C) (CH):СОН(aд) + Cl(aq) > (CH)3СCI'(aq) + ОН (aq) H'(aq) + ОН (аg) > H-О(1) D) (CH)3СОН(ад) + H'(ag) — (CH)3C(ОН)"(aд) (CH3)3C(OH2)*(aq) (CH3)3C(OH2)*(ag) → (CH3)3C*(ag) + H2O(1) (CH3)3C*(ag) + Cl(aq) → (CH3)3CCI(aq)
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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please explain every step of the process, i am very confused. (answer is D)
![Tert-butyl alcohol reacts with aqueous hydrochloric acid to give tert-butyl chloride as
shown below:
(CH3);COH(aq) +H*(aq) + Cl'(aq) → (CH3)3CCI(ag) + H2O(1)
For this reaction, rate = k[(CH3)3COH][H*]. With which mechanism is this rate law
consistent?
A) (CH3);COH(aq) + H*(aq)
(fast)
(slow)
(slow)
(fast)
(fast)
(slow)
(fast)
(fast)
(slow)
(fast)
E) None of these mechanisms are consistent with the rate law provided.
(CH3)3C(OH2)*(aq)
(CH3):C(ОН2)(аg) + Cl(aq) > (CH3):CC(ag) + H0()
в) (CH)3СОН(ад) > (СHз)3С(ag) + ОH-(aд)
(CH):С"(ag) + CI (ag) > (CH):ССI(ag)
H (aд) + ОН (aq) > H-О(1)
C) (CH):СОН(aд) + Cl(aq) > (CH)3СCI'(aq) + ОН (aq)
H'(aq) + ОН (аg) > H-О(1)
D) (CH)3СОН(ад) + H'(ag) — (CH)3C(ОН)"(aд)
(CH3)3C(OH2)*(aq)
(CH3)3C(OH2)*(ag) → (CH3)3C*(ag) + H2O(1)
(CH3)3C*(ag) + Cl(aq) → (CH3)3CCI(aq)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd47c799b-8bfb-40da-acef-498213782436%2F676976ab-6478-46ad-939a-3fb0f3db40d0%2Fgacushp.png&w=3840&q=75)
Transcribed Image Text:Tert-butyl alcohol reacts with aqueous hydrochloric acid to give tert-butyl chloride as
shown below:
(CH3);COH(aq) +H*(aq) + Cl'(aq) → (CH3)3CCI(ag) + H2O(1)
For this reaction, rate = k[(CH3)3COH][H*]. With which mechanism is this rate law
consistent?
A) (CH3);COH(aq) + H*(aq)
(fast)
(slow)
(slow)
(fast)
(fast)
(slow)
(fast)
(fast)
(slow)
(fast)
E) None of these mechanisms are consistent with the rate law provided.
(CH3)3C(OH2)*(aq)
(CH3):C(ОН2)(аg) + Cl(aq) > (CH3):CC(ag) + H0()
в) (CH)3СОН(ад) > (СHз)3С(ag) + ОH-(aд)
(CH):С"(ag) + CI (ag) > (CH):ССI(ag)
H (aд) + ОН (aq) > H-О(1)
C) (CH):СОН(aд) + Cl(aq) > (CH)3СCI'(aq) + ОН (aq)
H'(aq) + ОН (аg) > H-О(1)
D) (CH)3СОН(ад) + H'(ag) — (CH)3C(ОН)"(aд)
(CH3)3C(OH2)*(aq)
(CH3)3C(OH2)*(ag) → (CH3)3C*(ag) + H2O(1)
(CH3)3C*(ag) + Cl(aq) → (CH3)3CCI(aq)
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