Table 1. Reaction rates of various RTS formation runs at 30 °c. Concentration of solution before mixing Initial rate Run [Ra], M [Th], M [Ls], M x10-4 M/s 0.30 0.90 0.30 1.5 0.60 0.90 0.60 6.0 0.60 0.30 0.90 2.0 Using all available information, determine the: a. order with respect to Ls: b. order with respect to Ra (round off to the nearest whole number): C. order with respect to Th (round off to the nearest whole number): d. reactants most probably involved in the rate determining step of the mechanism: Th Ls Ra RTS e. average rate constant (use the rounded off reaction orders; express final answer in 2 SF, no need to include units in typing your answer here but it should be shown on your solution sheet): f. time (s) it took for Run 1 to turn red if a [RTS] of 0.010 M gives apparent coloration to the mixture (express final answer in 2 SF): seconds 23

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Chapter1: Chemical Foundations
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1.0E-04
5.0E-05
0.0E+00
0.1
0.15
0.2
0.25
0.3
0.35
[Ls), M
Figure 1. Rate of the reaction with respect to Ls (T=30 °C).
Table 1. Reaction rates of various RTS formation runs at 30 °C.
Concentration of solution before mixing
Initial rate
Run
[Ra], M
[Th], M
[Ls], M
x10-4 M/s
1
0.30
0.90
0.30
1.5
0.60
0.90
0.60
6.0
3.
0.60
0.30
0.90
2.0
Using all available information, determine the:
a. order with respect to Ls:
b. order with respect to Ra (round off to the nearest whole number):
C. order with respect to Th (round off to the nearest whole number):
d. reactants most probably involved in the rate determining step of the mechanism:
Th
Ls
Ra
RTS
e. average rate constant (use the rounded off reaction orders; express final answer in 2 SF, no need
to include units in typing your answer here but it should be shown on your solution sheet):
f. time (s) it took for Run 1 to turn red if a [RTS] of 0.010 M gives apparent coloration to the mixture
(express final answer in 2 SF):
seconds
Initial rate
Transcribed Image Text:1.0E-04 5.0E-05 0.0E+00 0.1 0.15 0.2 0.25 0.3 0.35 [Ls), M Figure 1. Rate of the reaction with respect to Ls (T=30 °C). Table 1. Reaction rates of various RTS formation runs at 30 °C. Concentration of solution before mixing Initial rate Run [Ra], M [Th], M [Ls], M x10-4 M/s 1 0.30 0.90 0.30 1.5 0.60 0.90 0.60 6.0 3. 0.60 0.30 0.90 2.0 Using all available information, determine the: a. order with respect to Ls: b. order with respect to Ra (round off to the nearest whole number): C. order with respect to Th (round off to the nearest whole number): d. reactants most probably involved in the rate determining step of the mechanism: Th Ls Ra RTS e. average rate constant (use the rounded off reaction orders; express final answer in 2 SF, no need to include units in typing your answer here but it should be shown on your solution sheet): f. time (s) it took for Run 1 to turn red if a [RTS] of 0.010 M gives apparent coloration to the mixture (express final answer in 2 SF): seconds Initial rate
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