Sulfuryl chloride (SO,Cl,) is a colorless liquid that boils at 69°C. Above this temperature, the vapors dissociate into sulfur dioxide and chlorine: SO,C2(g) 2 SO2(g) + Cl2(g) This reaction is slow at 100°C, but it is accelerated by the presence of some FeCl; (which does not affect the final position of the equilibrium). In an experiment, 3.174 g of SO,Cl2(e) and a small amount of solid FeCl; are put into an evacuated 1.000-L flask, which is then sealed and heated to 100°C. The total pressure in the flask at that temperature is found to be 1.30 atm. (a) Calculate the partial pressure of each of the three gases present. (b) Calculate the equilibrium constant at this temperature.

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Sulfuryl chloride (SO,Cl,) is a colorless liquid that boils at
69°C. Above this temperature, the vapors dissociate into
sulfur dioxide and chlorine:
SO,C2(g) 2 SO2(g) + Cl2(g)
This reaction is slow at 100°C, but it is accelerated by the
presence of some FeCl; (which does not affect the final
position of the equilibrium). In an experiment, 3.174 g of
SO,Cl2(e) and a small amount of solid FeCl; are put into
an evacuated 1.000-L flask, which is then sealed and
heated to 100°C. The total pressure in the flask at that
temperature is found to be 1.30 atm.
(a) Calculate the partial pressure of each of the three
gases present.
(b) Calculate the equilibrium constant at this temperature.
Transcribed Image Text:Sulfuryl chloride (SO,Cl,) is a colorless liquid that boils at 69°C. Above this temperature, the vapors dissociate into sulfur dioxide and chlorine: SO,C2(g) 2 SO2(g) + Cl2(g) This reaction is slow at 100°C, but it is accelerated by the presence of some FeCl; (which does not affect the final position of the equilibrium). In an experiment, 3.174 g of SO,Cl2(e) and a small amount of solid FeCl; are put into an evacuated 1.000-L flask, which is then sealed and heated to 100°C. The total pressure in the flask at that temperature is found to be 1.30 atm. (a) Calculate the partial pressure of each of the three gases present. (b) Calculate the equilibrium constant at this temperature.
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