Sulfuryl chloride (SO,Cl,) is a colorless liquid that boils at 69°C. Above this temperature, the vapors dissociate into sulfur dioxide and chlorine: SO,C2(g) 2 SO2(g) + Cl2(g) This reaction is slow at 100°C, but it is accelerated by the presence of some FeCl; (which does not affect the final position of the equilibrium). In an experiment, 3.174 g of SO,Cl2(e) and a small amount of solid FeCl; are put into an evacuated 1.000-L flask, which is then sealed and heated to 100°C. The total pressure in the flask at that temperature is found to be 1.30 atm. (a) Calculate the partial pressure of each of the three gases present. (b) Calculate the equilibrium constant at this temperature.

Sulfuryl chloride (SO,Cl,) is a colorless liquid that boils at 69°C. Above this temperature, the vapors dissociate into sulfur dioxide and chlorine: SO,C2(g) 2 SO2(g) + Cl2(g) This reaction is slow at 100°C, but it is accelerated by the presence of some FeCl; (which does not affect the final position of the equilibrium). In an experiment, 3.174 g of SO,Cl2(e) and a small amount of solid FeCl; are put into an evacuated 1.000-L flask, which is then sealed and heated to 100°C. The total pressure in the flask at that temperature is found to be 1.30 atm. (a) Calculate the partial pressure of each of the three gases present. (b) Calculate the equilibrium constant at this temperature.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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The Hammett analyses have been done on two substrates which obtain a rho value of 3.8. from the correlation with positive sigma constants (A) while the other set of substituents (B). has a rho value of -2 using the regular sigma values: part a) identify which rho value matches the substituents using resonance as an argument.