Substance KspKsp Sn(OH)2Sn(OH)2 Ksp=4S3=5.45×10−27Ksp=4S3=5.45×10−27 CuCNCuCN Ksp=S2=3.47×10−20Ksp=S2=3.47×10−20 MgF2MgF2 Ksp=4S3=5.16×10−11Ksp=4S3=5.16×10−11 NiCO3NiCO3 Ksp=S2=1.42×10−7 The equilibrium constants for the dissolution (KspKsp) of various substances in aqueous solution at 25°C are listed in the table above. Which of the following provides a correct comparison of the molar solubilities (SS) of some of these substances based on their Ksp ?
Types of Chemical Bonds
The attractive force which has the ability of holding various constituent elements like atoms, ions, molecules, etc. together in different chemical species is termed as a chemical bond. Chemical compounds are dependent on the strength of chemical bonds between its constituents. Stronger the chemical bond, more will be the stability in the chemical compounds. Hence, it can be said that bonding defines the stability of chemical compounds.
Polarizability In Organic Chemistry
Polarizability refers to the ability of an atom/molecule to distort the electron cloud of neighboring species towards itself and the process of distortion of electron cloud is known as polarization.
Coordinate Covalent Bonds
A coordinate covalent bond is also known as a dative bond, which is a type of covalent bond. It is formed between two atoms, where the two electrons required to form the bond come from the same atom resulting in a semi-polar bond. The study of coordinate covalent bond or dative bond is important to know about the special type of bonding that leads to different properties. Since covalent compounds are non-polar whereas coordinate bonds results always in polar compounds due to charge separation.
| Substance | KspKsp |
| Sn(OH)2Sn(OH)2 | Ksp=4S3=5.45×10−27Ksp=4S3=5.45×10−27 |
| CuCNCuCN | Ksp=S2=3.47×10−20Ksp=S2=3.47×10−20 |
| MgF2MgF2 | Ksp=4S3=5.16×10−11Ksp=4S3=5.16×10−11 |
| NiCO3NiCO3 | Ksp=S2=1.42×10−7 |
The equilibrium constants for the dissolution (KspKsp) of various substances in aqueous solution at 25°C are listed in the table above. Which of the following provides a correct comparison of the molar solubilities (SS) of some of these substances based on their Ksp ?
b.) The molar solubilities for CuCNCuCN and NiCO3NiCO3 are calculated using S=Ksp−−−√S=Ksp and CuCNCuCN has a lower molar solubility than NiCO3NiCO3.
c.) The molar solubilities for Sn(OH)2Sn(OH)2 and MgF2MgF2 are calculated using S=Ksp4−−−√S=Ksp4 and MgF2MgF2 has a lower molar solubility than NiCO3NiCO3.
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