Squaric acid has a pKa of 1.5, making it much more acidic than many carboxylic acids (typical pKa values of 4–5). One of the reasons for its acidity is resonance stabilization of its conjugate base, which is shown below. Add curved arrows to the structure on the left to show how it is converted to the other resonance contributor shown to the right.

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter5: Stereochemistry At Tetrahedral Centers
Section5.SE: Something Extra
Problem 26VC: Which of the following structures are identical? (Green = Cl.)
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Squaric acid has a pKa of 1.5, making it much more acidic than many carboxylic acids (typical pKa values of 4–5). One of the reasons for its acidity is resonance stabilization of its conjugate base, which is shown below. Add curved arrows to the structure on the left to show how it is converted to the other resonance contributor shown to the right.

ö:
ö:
Add curved arrows to the structure on the left to show how it is converted to the structure on the right.
2D
H
+
:ö.
F
P
CI
Br
H-
I
:ö.
Transcribed Image Text:ö: ö: Add curved arrows to the structure on the left to show how it is converted to the structure on the right. 2D H + :ö. F P CI Br H- I :ö.
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