Specify both the alcohol starting material and the reagents you would use in each step in a synthesis of the compound shown. If the synthesis requires only two steps enter "none" for step 3. Br Alcohol Starting Materials. 1, methanol 2. ethanol 3. 1-propanol 4. 2-propanol 5. cyclohexanol a. LIAIH4 b. H₂SO4 c. HCI d. HBr e. SOCI₂ Reagents Available f. PBr3 g. CrO3 h. NaH i. CH₂MgBr j. CH3CH₂MgBr k. CH3CH₂CH₂MgBr I. C6H5MgBr (phenylmagnesium bromide) m. (CH3)2CHMgBr n. pyridinium chlorochromate (PCC) Write the number/letters of the alchol/reagents in the boxes below. Alcohol starting material Reagent for step 1 Reagent for step 2 Reagent for step 3 Pa
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
![Specify both the alcohol starting material and the reagents you would use in each step in a synthesis of the compound shown. If the synthesis requires only two steps enter "none" for step 3.
Br
Alcohol Starting Materials
1. methanol
2. ethanol
3. 1-propanol
4. 2-propanol
5. cyclohexanol
a. LiAlH4
b. H₂SO4
c. HCI
d. HBr
e. SOCI₂
Reagent for step 2
Reagent for step 3
Reagents Available
f. PBr3
g. CrO3
h. NaH
i. CH3MgBr
j. CH3CH₂MgBr
k. CH₂CH₂CH₂MgBr
I. C6H5MgBr (phenylmagnesium
bromide)
m. (CH3)2CHMgBr
pyridinium chlorochromate (PCC)
Write the number/letters of the alchol/reagents in the boxes below.
Alcohol starting material
Reagent for step 1
Pa](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F98300f68-cb9e-4c94-97bf-c558b3a74855%2Fafba2304-a079-4e4c-9bbf-014a0a6d4b4c%2F0a2fqif_processed.jpeg&w=3840&q=75)
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