Solution of EDTA is particularly valuable as titrants because the reagent combines with metal ions in a 1:1 ratio regardless of the charge on the cation. For example, Fe(ll) and Fe(lII), complexes are formed with EDTA with great stability. The formation constants for the Fe(ll)-EDTA chelate, and Fe(llI)-EDTA chelate are 2.1 X 1014 and 1.3 X 1025, respectively. O For each ion complex mentioned above, write the equations of reactions for complex formation and expression for the complex formation constant. O Calculate the concentration of Fe3+ in a solution that was prepared by mixing 50.0 mL of 0.200 M Fe3+ with 200,0 ml of 0.0100 M EDTA. The mixture was buffered to a pH of 11.00. (Given the value of a, = 0.85 at pH 11.00)
Solution of EDTA is particularly valuable as titrants because the reagent combines with metal ions in a 1:1 ratio regardless of the charge on the cation. For example, Fe(ll) and Fe(lII), complexes are formed with EDTA with great stability. The formation constants for the Fe(ll)-EDTA chelate, and Fe(llI)-EDTA chelate are 2.1 X 1014 and 1.3 X 1025, respectively. O For each ion complex mentioned above, write the equations of reactions for complex formation and expression for the complex formation constant. O Calculate the concentration of Fe3+ in a solution that was prepared by mixing 50.0 mL of 0.200 M Fe3+ with 200,0 ml of 0.0100 M EDTA. The mixture was buffered to a pH of 11.00. (Given the value of a, = 0.85 at pH 11.00)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:1.Solution of EDTA is particularly valuable as titrants because the reagent
combines with metal ions in a 1:1 ratio regardless of the charge on the
cation. For example, Fe(ll) and Fe(lll), complexes are formed with EDTA
with great stability. The formation constants for the Fe(ll)-EDTA chelate,
and Fe(lll)-EDTA chelate are 2.1 × 1014 and 1.3 × 1025, respectively.
a) For each ion complex mentioned above, write the equations of reactions
for complex formation and expression for the complex formation
constant.
b) Calculate the concentration of Fe3+ in a solution that was prepared by
mixing 50.0 mL of 0.200 M Fe3+ with 200,0 m of 0.0100 M EDTA. The
mixture was buffered to a pH of 11.00.
(Given the value of a, = 0.85 at pH 11.00)
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