Solution of EDTA is particularly valuable as titrants because the reagent combines with metal ions in a 1:1 ratio regardless of the charge on the cation. For example, Fe(ll) and Fe(ll), complexes are formed with EDTA with great stability. The formation constants for the Fe(ll)-EDTA chelate, and Fe(lll)-EDTA chelate are 2.1 X 1014 and 1.3 x 1025, respectively. O For each ion complex mentioned above, write the equations of reactions for complex formation and expression for the complex formation constant. ) Calculate the concentration of Fe* in a solution that was prepared by mixing 50.0 mL of 0.200 M Fe* with 200 0 oo0.0100 M EDTA. The mixture was buffered to a pH of 11.00. (Given the value of a, = 0.85 al pH 11.00)

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1.Solution of EDTA is particularly valuable as titrants because the reagent
combines with metal ions in a 1:1 ratio regardless of the charge on the
cation. For example, Fe(ll) and Fe(ll), complexes are formed with EDTA
with great stability. The formation constants for the Fe(ll)-EDTA chelate,
and Fe(lll)-EDTA chelate are 2.1 x 1014 and 1.3 X 1025, respectively.
a) For each ion complex mentioned above, write the equations of reactions
for complex formation and expression for the complex formation
constant.
b) Calculate the concentration of Fet In a solution that was prepared by
mixing 50.0 mL of 0.200 M Fohwith 200 0 o/oro.0100 M EDTA. The
mixture was buffered to a ph of 11.00,
(Given the valio of a, 0.85 al pH I1.00)
Transcribed Image Text:1.Solution of EDTA is particularly valuable as titrants because the reagent combines with metal ions in a 1:1 ratio regardless of the charge on the cation. For example, Fe(ll) and Fe(ll), complexes are formed with EDTA with great stability. The formation constants for the Fe(ll)-EDTA chelate, and Fe(lll)-EDTA chelate are 2.1 x 1014 and 1.3 X 1025, respectively. a) For each ion complex mentioned above, write the equations of reactions for complex formation and expression for the complex formation constant. b) Calculate the concentration of Fet In a solution that was prepared by mixing 50.0 mL of 0.200 M Fohwith 200 0 o/oro.0100 M EDTA. The mixture was buffered to a ph of 11.00, (Given the valio of a, 0.85 al pH I1.00)
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