Sodium hypochlorite (NaOCl, the oxidant in household bleach) in aqueous CH3COOH is also touted as a “green” oxidizing agent. For example, oxidation of (CH3)2CHOH with NaOCl forms (CH3)2C = O along with NaCl and H2O. (a) What advantages and/or disadvantages does this method have over oxidation with HCrO4- –Amberlyst A-26 resin? (b) What advantages and/or disadvantages does this method have over oxidation with CrO3, H2SO4, H2O?

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Sodium hypochlorite (NaOCl, the oxidant in household bleach) in aqueous CH3COOH is also touted as a “green” oxidizing agent. For example, oxidation of (CH3)2CHOH with NaOCl forms (CH3)2C = O along with NaCl and H2O. (a) What advantages and/or disadvantages does this method have over oxidation with HCrO4- –Amberlyst A-26 resin? (b) What advantages and/or disadvantages does this method have over oxidation with CrO3, H2SO4, H2O?

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