(Show or describe your work) Suppose the reaction A <__> B has an equilibrium constant of Keq = [B] eq/[A] eq. The forward reaction proceeds to the right by an uncatalyzed pathway with a rate = kof[A] AND by a proton- catalyzed pathway with a rate = kHf[H+][A]. Thus the overall rate law for the forward reaction involves the sum of these two terms. ? =(??? +???[?+])[?]=??[?] What is the corresponding rate law for the backward reactions?

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Polymerization Kinetics

Polymerization is a chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that diverge in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes. Polymerization is generally classified into step-growth and chain polymerization. Polymers are categorized into linear polymer and cross-linked polymers that are produced either by condensation or additional polymerization.