se the image below to answer the following three questions. Note: Subscripts are not shown in nswer choices, ex: H2 should be H2, NH3 should be NH3. ? Product A Product B Product C The reagents that would selectively yield Product A are H2, Lindlar's catalyst The reagents that would selectively yield Product B are Na, NH3, -78°C . The reagents that would selectively yield Product C are H2, Pd/C
se the image below to answer the following three questions. Note: Subscripts are not shown in nswer choices, ex: H2 should be H2, NH3 should be NH3. ? Product A Product B Product C The reagents that would selectively yield Product A are H2, Lindlar's catalyst The reagents that would selectively yield Product B are Na, NH3, -78°C . The reagents that would selectively yield Product C are H2, Pd/C
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:### Organic Chemistry: Selective Hydrogenation of Alkynes
#### Problem Statement:
Use the image below to answer the following three questions. **Note:** Subscripts are not shown in answer choices, e.g., H2 should be H₂, NH3 should be NH₃.
#### Reaction Scheme:
1. Starting Material: A molecule with a terminal alkyne group is given.
2. The reaction leading to the product is unspecified (a question mark is shown).
3. Possible Products:
- **Product A**: Contains a double bond (cis-alkene).
- **Product B**: Contains a double bond (trans-alkene).
- **Product C**: A fully saturated hydrocarbon with no double or triple bonds.
#### Questions:
a. The reagents that would selectively yield **Product A** are:
- **Answer**: H₂, Lindlar's catalyst.
b. The reagents that would selectively yield **Product B** are:
- **Answer**: Na, NH₃, -78°C.
c. The reagents that would selectively yield **Product C** are:
- **Answer**: H₂, Pd/C.
#### Explanation of Graphical Elements:
The image contains a chemical structure followed by a question mark to indicate an unspecified reaction, leading to three distinct products labeled as Product A, Product B, and Product C. The choices for reagents are given in a drop-down format for each product.
1. **Product A** contains a cis-double bond. The selective hydrogenation of the alkyne using H₂ and Lindlar's catalyst results in a cis-alkene.
2. **Product B** contains a trans-double bond. The selective hydrogenation of the alkyne with Na in liquid NH₃ at -78°C results in a trans-alkene.
3. **Product C** is a fully hydrogenated alkane, achieved by using H₂ with a palladium on carbon (Pd/C) catalyst.
This curated information directs the student to understand the methods used in selective hydrogenation of alkynes, focusing on the role of different catalytic and reagent conditions.
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