Salt MgCO3 Mg(OH)2 Theoretical Ksp 3.5 x 10-8 1.8 x 10-11 For the standardization of the HCI titrant, 5.230 mg Na2CO3 (98.9% purity, MW = 105.99 g/mol) required 24.4 mL of the titrant to reach the phenolphthalein endpoint. After isolating and precipitating the magnesium salt A, a portion was dissolved in distilled water in order to make a 250.0-mL saturated solution. The titration of a 50.0-mL aliquot of the saturated solution required 8.20 mL of HCl titrant to reach the phenolphthalein endpoint. Meanwhile, dissolving this magnesium salt in 250.0 mL of 0.0200 M MgCl₂ required 1.51 mL of the same HCl titrant to titrate a 100.0-ml solution. a. What is the molarity of the HCI titrant? b. Comparing the data in distilled water with the two possible solids, which is the most likely identity of the magnesium salt? Show your full solutions in getting your conclusion. Note: Don't forget to factor in stoichiometry c. What is the average experimental Ksp for both solvents (distilled water and 0.0200 M MgCl2) and individual solubility in each solvent of the magnesium salt? d. What is the percent error in the obtained Ksp value?..
Salt MgCO3 Mg(OH)2 Theoretical Ksp 3.5 x 10-8 1.8 x 10-11 For the standardization of the HCI titrant, 5.230 mg Na2CO3 (98.9% purity, MW = 105.99 g/mol) required 24.4 mL of the titrant to reach the phenolphthalein endpoint. After isolating and precipitating the magnesium salt A, a portion was dissolved in distilled water in order to make a 250.0-mL saturated solution. The titration of a 50.0-mL aliquot of the saturated solution required 8.20 mL of HCl titrant to reach the phenolphthalein endpoint. Meanwhile, dissolving this magnesium salt in 250.0 mL of 0.0200 M MgCl₂ required 1.51 mL of the same HCl titrant to titrate a 100.0-ml solution. a. What is the molarity of the HCI titrant? b. Comparing the data in distilled water with the two possible solids, which is the most likely identity of the magnesium salt? Show your full solutions in getting your conclusion. Note: Don't forget to factor in stoichiometry c. What is the average experimental Ksp for both solvents (distilled water and 0.0200 M MgCl2) and individual solubility in each solvent of the magnesium salt? d. What is the percent error in the obtained Ksp value?..
Chapter12: Spectrochemical Methods
Section: Chapter Questions
Problem 15P
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