Jj.65. сdO i, aabHow would you carry out the following transformation using reagents from the table?HTransformation:CNReagents:1. NaOH/H₂O2. H₂O*1. BH3/THF2. H₂O₂/NaOHPBr3O a, e, hO a, dO a, f, dDess-Martinperiodinane in CH₂Cl₂f9h1. BH₂/THF2. H₂O*1. LIAIH2. H₂O*NaCNCrO₂/H₂O*1JkI1. NaBH2. H₂O*1. CH₂CH₂MgBr / dry ether2. H₂O*1. (CH3)2CHMgBr / dry ether2. H₂Oconc. HCI

Carboxylic acid on reduction with LiAlH4 gives alcohol which on treatment with Dess Martin reagent…

с d a b Oi, a Reagents: Oa, d a, f, d QUESTION 11 How would you carry out the following transformation using reagents from the table? Transformation: CN a, e, h 1. NaOH/H₂0 2. H₂O* 1. BH3/THF 2. H₂O₂/NaOH PBr3 Dess-Martin periodinane in CH₂Cl₂ f 9 h 1. BH₂/THF 2. H₂O* 1. LIAIH 2. H₂O* NaCN CrO3/H₂O* 1 J k I 1. NaBH4 2. H₂O* 1. CH₂CH₂MgBr / dry ether 2. H₂O* 1. (CH3)2CHMgBr / dry ether 2. H₂O conc. HCI

с d a b Oi, a Reagents: Oa, d a, f, d QUESTION 11 How would you carry out the following transformation using reagents from the table? Transformation: CN a, e, h 1. NaOH/H₂0 2. H₂O* 1. BH3/THF 2. H₂O₂/NaOH PBr3 Dess-Martin periodinane in CH₂Cl₂ f 9 h 1. BH₂/THF 2. H₂O* 1. LIAIH 2. H₂O* NaCN CrO3/H₂O* 1 J k I 1. NaBH4 2. H₂O* 1. CH₂CH₂MgBr / dry ether 2. H₂O* 1. (CH3)2CHMgBr / dry ether 2. H₂O conc. HCI

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Amines

Amines are organic compounds with a nitrogen atom having a lone pair of electrons on it. They are derived from ammonia (NH3) wherein hydrogen atoms are substituted by an aryl or alkyl group.

Question

Jj.65.

с
d
O i, a
a
b
How would you carry out the following transformation using reagents from the table?
H
Transformation:
CN
Reagents:
1. NaOH/H₂O
2. H₂O*
1. BH3/THF
2. H₂O₂/NaOH
PBr3
O a, e, h
O a, d
O a, f, d
Dess-Martin
periodinane in CH₂Cl₂
f
9
h
1. BH₂/THF
2. H₂O*
1. LIAIH
2. H₂O*
NaCN
CrO₂/H₂O*
1
J
k
I
1. NaBH
2. H₂O*
1. CH₂CH₂MgBr / dry ether
2. H₂O*
1. (CH3)2CHMgBr / dry ether
2. H₂O
conc. HCI

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