Calculate the H (in kcal/mol) for the reactions (use table 7.1): • H2 + O2 ------ 2 H2O • CH4 + • 6 CO2 + 2O2 ------ CO2 + 2 H2O 6H2O ------ C6H12O6 + 6O2

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Calculate the H (in kcal/mol) for the reactions (use table 7.1): • H2 + O2 ------ 2 H2O

• CH4 +

• 6 CO2 +

2O2 ------ CO2 + 2 H2O

6H2O ------ C6H12O6 + 6O2

 

 

7:21 1
Q A AA
:N:::N: + 226 kcal/mol →
+ •N:
N, bond dissociation energy = 226 kcal/mol (946 kJ/mol)
:Cl:Cl: + 58 kcal/mol →
•CI: Cl, bond dissociation energy = 58 kcal/mol (243 kJ/mol)
The greater stability of the triple bond in N, ex-
plains why nitrogen molecules are less reactive
than Cl, molecules. Some typical bond dissocia-
tion energies are given in Table 7.10.
Table 7.1 Average Bond Dissociation
Energies
Bond Dissociation
Bond Dissociation
Bond Dissociation
Energy
Energy
Energy
kcal /mol (kJ/mol)
Bond
kcal/mol (kJ/mol)
Bond
kcal/mol (kJ/mol)
Bond
C-H
99 (413)
N-H
93 (391)
c=C
147 (614)
С —с
83 (347)
N-N
38 (160)
C=C
201 (839)
C-N
73 (305)
N-CI
48 (200)
C=0*
178 (745)
C-0
86 (358)
N-0
48 (201)
0=0
119 (498)
C-CI
81 (339)
H-H
103 (432)
N=0
145 (607)
CI
CI
58 (243)
0-H
112 (467)
0=N
213 (891)
H
CI
102 (427)
0-CI
49 (203)
N=N
226 (946)
*The C = 0 bond dissociation energies in Co, are 191 kcal/mol
(799 kJ/mol).
A chemical change that absorbs heat, like the
breaking of bonds, is endothermic, from the
Greek words endon (within) and therme (heat),
meaning that heat is required as a condition for
reaction and would appear on the left side of the
equation. The reverse of bond breaking is bond
formation, a process that releases heat and is
exothermic, from the Greek exo (outside),
Transcribed Image Text:7:21 1 Q A AA :N:::N: + 226 kcal/mol → + •N: N, bond dissociation energy = 226 kcal/mol (946 kJ/mol) :Cl:Cl: + 58 kcal/mol → •CI: Cl, bond dissociation energy = 58 kcal/mol (243 kJ/mol) The greater stability of the triple bond in N, ex- plains why nitrogen molecules are less reactive than Cl, molecules. Some typical bond dissocia- tion energies are given in Table 7.10. Table 7.1 Average Bond Dissociation Energies Bond Dissociation Bond Dissociation Bond Dissociation Energy Energy Energy kcal /mol (kJ/mol) Bond kcal/mol (kJ/mol) Bond kcal/mol (kJ/mol) Bond C-H 99 (413) N-H 93 (391) c=C 147 (614) С —с 83 (347) N-N 38 (160) C=C 201 (839) C-N 73 (305) N-CI 48 (200) C=0* 178 (745) C-0 86 (358) N-0 48 (201) 0=0 119 (498) C-CI 81 (339) H-H 103 (432) N=0 145 (607) CI CI 58 (243) 0-H 112 (467) 0=N 213 (891) H CI 102 (427) 0-CI 49 (203) N=N 226 (946) *The C = 0 bond dissociation energies in Co, are 191 kcal/mol (799 kJ/mol). A chemical change that absorbs heat, like the breaking of bonds, is endothermic, from the Greek words endon (within) and therme (heat), meaning that heat is required as a condition for reaction and would appear on the left side of the equation. The reverse of bond breaking is bond formation, a process that releases heat and is exothermic, from the Greek exo (outside),
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