[Review Topics) [References) Specify the types of strain that destabilize the conformer shown below. Hint: All bonds not explicitly shown are in th staggered conformation. 1. Torsional strain 2. Angle (ring) strain 3. Steric (van der Waals) strain H. H3C. CH3 CH3
[Review Topics) [References) Specify the types of strain that destabilize the conformer shown below. Hint: All bonds not explicitly shown are in th staggered conformation. 1. Torsional strain 2. Angle (ring) strain 3. Steric (van der Waals) strain H. H3C. CH3 CH3
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Torsional strain is generated when two groups are placed at 1 and 3 positions with respect to eachother .
Thus this strain is more prominent for equitorial bonds
In small rings like cyclopropane , cyclobutane etc
Bond angle predicted from ring size is less than that expected from hybridization state. Thus angle strain is generated.
Steric strain is generated if two large groups are in close proximity i.e. within an angle of 0- 60°
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