Of the two unimolecular reactions shown, decide whichwould have a higher relative rate constant (krel). Basedon your answer, draw two lines on one reactioncoordinate diagram that show the relative progress ofeach reaction along its path to product indicated andexplain why the reaction you chose is faster. Yourresponse should address following issues: a) Bonddissociation energy of the C - LG bond. b) Nature of theleaving group (LG). c) The relative size of activationenergy (Ea) for each reaction d) Hammond's postulate.e) Relative thermodynamic stability of the reactiveintermediates. f) Influence of the solvent (if given) onthe reactions and intermediates.BrCHBr (1)(2)

We have found out the answer according to size of the leaving group and stability of carbocation in…

response should address following issues: a) Bond dissociation energy of the C-LG bond. b) Nature of the leaving group (LG). c) The relative size of activation energy (Ea) for each reaction d) Hammond's postulate. e) Relative thermodynamic stability of the reactive intermediates. f) Influence of the solvent (if given) on the reactions and intermediates. C C (1) (2)

response should address following issues: a) Bond dissociation energy of the C-LG bond. b) Nature of the leaving group (LG). c) The relative size of activation energy (Ea) for each reaction d) Hammond's postulate. e) Relative thermodynamic stability of the reactive intermediates. f) Influence of the solvent (if given) on the reactions and intermediates. C C (1) (2)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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