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b. C. Br + HO™ CH₂CH₂CH₂CH₂Br 1 1. CEN 2. H₂, Raney Ni

b. C. Br + HO™ CH₂CH₂CH₂CH₂Br 1 1. CEN 2. H₂, Raney Ni

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**22. What are the products of the following reactions?** **a.** Reaction between a pyrrole derivative and benzoyl chloride. - Reactants: Pyrrole with a hydrogen atom and benzoyl chloride. - Condition: Reaction proceeds with 2 equivalents of pyrrole. **b.** Quinol ine derivative reaction with hydroxide. - Reactants: Quinoline with a bromine atom and hydroxide ion (HO⁻). - Condition: The reaction has a delta (Δ) symbol indicating heat. **c.** Propyl bromide reaction with hydrogen cyanide and hydrogen over Raney nickel. - Reactants: Propyl bromide and hydrogen cyanide (C≡N). - Conditions: The reaction has two steps. 1. Reaction with C≡N 2. Reduction with hydrogen (H₂) in the presence of Raney nickel (Ra-Ni). **d.** Reaction between an epoxide and acetyl chloride. - Reactants: Epoxide and acetyl chloride (CH₃COCl). - Conditions: The reaction proceeds in two steps. 1. Addition of boron trifluoride (BF₃) in tetrahydrofuran (THF). 2. Addition of water (H₂O). **e.** Pyridine derivative reaction with C₆H₅Li. - Reactants: Chloropyridine and phenyl lithium. **f.** Reaction between aniline and butyl bromide. - Reactants: Aniline (with an NH₂ group) and butyl bromide (CH₃CH₂CH₂CH₂Br). **g.** Pyrrole reaction with phenylmagnesium bromide. - Reactants: Pyrrole and phenyl magnesium bromide (C₆H₅MgBr). **h.** Methylpyrrolidine reaction with ethyl bromide. - Reactants: Methylpyrrolidine and ethyl bromide (CH₃CH₂CH₂Br). - Conditions: Ammonia is used in the first step. **i.** Reaction of a thiophene derivative with magnesium in diethyl ether, followed by CO₂ and HCl. - Reactants: Bromothiophene and magnesium. - Conditions: The reaction proceeds in three steps. 1. Reaction with magnesium in diethyl ether (Mg/Et₂O). 2
Transcribed Image Text:**22. What are the products of the following reactions?** **a.** Reaction between a pyrrole derivative and benzoyl chloride. - Reactants: Pyrrole with a hydrogen atom and benzoyl chloride. - Condition: Reaction proceeds with 2 equivalents of pyrrole. **b.** Quinol ine derivative reaction with hydroxide. - Reactants: Quinoline with a bromine atom and hydroxide ion (HO⁻). - Condition: The reaction has a delta (Δ) symbol indicating heat. **c.** Propyl bromide reaction with hydrogen cyanide and hydrogen over Raney nickel. - Reactants: Propyl bromide and hydrogen cyanide (C≡N). - Conditions: The reaction has two steps. 1. Reaction with C≡N 2. Reduction with hydrogen (H₂) in the presence of Raney nickel (Ra-Ni). **d.** Reaction between an epoxide and acetyl chloride. - Reactants: Epoxide and acetyl chloride (CH₃COCl). - Conditions: The reaction proceeds in two steps. 1. Addition of boron trifluoride (BF₃) in tetrahydrofuran (THF). 2. Addition of water (H₂O). **e.** Pyridine derivative reaction with C₆H₅Li. - Reactants: Chloropyridine and phenyl lithium. **f.** Reaction between aniline and butyl bromide. - Reactants: Aniline (with an NH₂ group) and butyl bromide (CH₃CH₂CH₂CH₂Br). **g.** Pyrrole reaction with phenylmagnesium bromide. - Reactants: Pyrrole and phenyl magnesium bromide (C₆H₅MgBr). **h.** Methylpyrrolidine reaction with ethyl bromide. - Reactants: Methylpyrrolidine and ethyl bromide (CH₃CH₂CH₂Br). - Conditions: Ammonia is used in the first step. **i.** Reaction of a thiophene derivative with magnesium in diethyl ether, followed by CO₂ and HCl. - Reactants: Bromothiophene and magnesium. - Conditions: The reaction proceeds in three steps. 1. Reaction with magnesium in diethyl ether (Mg/Et₂O). 2
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22. What are the products of the following reactions? a. 2 b. Br +HO c. CH₂CH₂CH₂CH₂Br 1. C=N 2. H₂, Raney Ni f. CH₂ CH₂ NH₂ CHsLi 1. BF₂/THF C 2. H₂0 + CH₂CH₂CH₂Br + C6H5N=N CH3 1. NH₂ 2. CH₂CH₂CH₂Br 1. Mg/Et₂O Br 2. CO₂ 3. HCI
Transcribed Image Text:22. What are the products of the following reactions? a. 2 b. Br +HO c. CH₂CH₂CH₂CH₂Br 1. C=N 2. H₂, Raney Ni f. CH₂ CH₂ NH₂ CHsLi 1. BF₂/THF C 2. H₂0 + CH₂CH₂CH₂Br + C6H5N=N CH3 1. NH₂ 2. CH₂CH₂CH₂Br 1. Mg/Et₂O Br 2. CO₂ 3. HCI
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