reactants and products, determine which direction the each of the following reaction proceed? Use the table of acid-conjugate strength (NOT Ka) to explain your answer. CH3-(aq) + CH3CO2H (aq)  -> CH3CO2-(aq) + CH4(aq)

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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  If you mix equal amount concentrations of reactants and products, determine which direction the
each of the following reaction proceed? Use the table of acid-conjugate strength (NOT Ka) to explain your
answer.
CH3-(aq) + CH3CO2H (aq)  -> CH3CO2-(aq) + CH4(aq) 

Trend in conjugate acid-base strength opposite
Relative acid strength
Stronger
acids
Weaker
H,0*
HCIO2
HF
H,CO3
CH,COOH
NH,
HPO
H20
acids
Ka
10-2
10-12
1.0
10-4
10-6
10-8
10-10
10-14
Relative conjugate base strength
Weaker
CIO,
HCO3
CH,CO0
PO,3-
Stronger
bases
H20
NH3
ОН
bases
К, 10-14
10-12
10 4
10-10
10-8
10-6
10-2
1.0
Acid
Base
perchloric acid
HCIO4
CIO,
perchlorate ion
sulfuric acid
H2SO4
HSO,
hydrogen sulfate ion
Undergo
complete
acid
Do not
undergo
hydrogen iodide
HI
iodide ion
base
hydrogen bromide
HBr
Br
bromide ion
ionization
in water
ionization
hydrogen chloride
HCI
in water
CI
chloride ion
nitric acid
HNO3
NO3
nitrate ion
hydronium ion
H30*
H2O
water
hydrogen sulfate ion
HSO,
so?-
sulfate ion
phosphoric acid
H3PO4
H„PO,
dihydrogen phosphate ion
hydrogen fluoride
HE
fluoride ion
nitrous acid
HNO,
NO,
nitrite ion
acetic acid
CH;CO,H
CH3CO,
acetate ion
carbonic acid
H,CO3
HCO3
hydrogen carbonate ion
hydrogen sulfide
H2S
HS
hydrogen sulfide ion
ammonium ion
NHA
NH3
ammonia
hydrogen cyanide
НCN
CN-
cyanide ion
hydrogen carbonate ion
HCO3
co-
carbonate ion
water
H20
OH
hydroxide ion
hydrogen sulfide ion
HS
s²-
sulfide ion
Do not
undergo
Undergo
complete
ethanol
C2H5OH
ethoxide ion
ammonia
NH3
acid
base
NH,
amide ion
ionization
ionization
hydrogen
H2
hydride ion
in water
in water
methane
CH4
CH3
methide ion
Increasing acid strength
Increasing base strength
Transcribed Image Text:Trend in conjugate acid-base strength opposite Relative acid strength Stronger acids Weaker H,0* HCIO2 HF H,CO3 CH,COOH NH, HPO H20 acids Ka 10-2 10-12 1.0 10-4 10-6 10-8 10-10 10-14 Relative conjugate base strength Weaker CIO, HCO3 CH,CO0 PO,3- Stronger bases H20 NH3 ОН bases К, 10-14 10-12 10 4 10-10 10-8 10-6 10-2 1.0 Acid Base perchloric acid HCIO4 CIO, perchlorate ion sulfuric acid H2SO4 HSO, hydrogen sulfate ion Undergo complete acid Do not undergo hydrogen iodide HI iodide ion base hydrogen bromide HBr Br bromide ion ionization in water ionization hydrogen chloride HCI in water CI chloride ion nitric acid HNO3 NO3 nitrate ion hydronium ion H30* H2O water hydrogen sulfate ion HSO, so?- sulfate ion phosphoric acid H3PO4 H„PO, dihydrogen phosphate ion hydrogen fluoride HE fluoride ion nitrous acid HNO, NO, nitrite ion acetic acid CH;CO,H CH3CO, acetate ion carbonic acid H,CO3 HCO3 hydrogen carbonate ion hydrogen sulfide H2S HS hydrogen sulfide ion ammonium ion NHA NH3 ammonia hydrogen cyanide НCN CN- cyanide ion hydrogen carbonate ion HCO3 co- carbonate ion water H20 OH hydroxide ion hydrogen sulfide ion HS s²- sulfide ion Do not undergo Undergo complete ethanol C2H5OH ethoxide ion ammonia NH3 acid base NH, amide ion ionization ionization hydrogen H2 hydride ion in water in water methane CH4 CH3 methide ion Increasing acid strength Increasing base strength
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