3. Reactants A-B and B-C react according to the equation below. In what orientationmust the reactant particles collide in order to be effective? Be sure todraw the collision (activated complex), and use a dotted line for any bonds beingmade or being broken.A-B +В-С→ A-C2 B

Collision is generally the theory used to predict the rates of chemical reactions, particularly for…

Answered: Reactants A-B and B-C react according…

Biochemistry

9th Edition

ISBN:9781319114671

Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.

Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.

Chapter1: Biochemistry: An Evolving Science

Section: Chapter Questions

Problem 1P

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Based on the intermediates outlined below, suggest why in different solvents and at different pH they are either soluble or insoluble.
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Draw all three staggered conformations for the following compound, viewed along the C₂-C3 bond. Determine which conformation is the most stable, taking into account gauche interactions and hydrogen-bonding interactions. (J. Phys. Chem. A 2001, 105, 6991-6997) Provide a reason for your choice by identifying all of the interactions that led to your decision. H H&COH C₂ C3 HỌ CH CH3 Which of the following is the most stable staggered conformer? Me H OH Me OH Me- Me Me H Conformer A OH OH OH HO H H H Conformer B Conformer C Me Conformer B because the anti OH groups avoid hydrogen bonding, which is a destabilizing effect. Conformer A because there are only two gauche interactions, and hydrogen bonding between the two OH groups is a stabilizing effect. Conformer C because there is no steric strain for Me-OH gauche interactions and hydrogen bonding between the two OH groups is a stabilizing effect. Conformer B because the large OH groups are anti to each other.
Using collision theory, indicate which of the following statements regarding physical nature of the reactants is true: a) physical nature of reactants The physical nature of reactants does not influence the rate of reaction because reactions happen only on the molecular level. Solids, liquids or gases all influence the rate of reaction the same because they are all in the physical state. Solid state reactants react faster if the particle sizes are larger because reactions occur at the boundary surface with direct contact. Gaseous-state reactions are faster than liquid-state or solid-state reactions because collisions between reactants are more frequent.

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Reactants A-B and B-C react according to the equation below. In what orientation must the reactant particles collide in order to be effective? Be sure to draw the collision (activated complex), and use a dotted line for any bonds being made or being broken. А-B B-C A-C 2 B