Rank the following compounds in order from most stable to least stable: Rank these compounds from most stable to least stable. Reset Help + + + most stable least stable O The correct ranking cannot be determined.
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
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![**Activity: Ranking Compound Stability**
**Objective:**
Rank the following compounds in order from most stable to least stable.
**Instructions:**
Below are three skeletal structures of carbocations. Your task is to rank these carbocations based on their stability.
**Compounds:**
1. **First Structure:** A linear chain with a positively charged carbon (indicated by a plus sign) in the middle. No double bonds are associated with this carbon.
2. **Second Structure:** A similar linear chain, but this time there is one double bond adjacent to the positively charged carbon.
3. **Third Structure:** A linear chain with two double bonds adjacent to the positively charged carbon.
**Task:**
Drag and drop these structures into the box below to arrange them from most stable on the left to least stable on the right.
**Additional Option:**
- Check the box if you determine that the correct ranking cannot be established from the given information.
**Explanation:**
Carbocation stability generally increases with greater alkyl substitution and resonance stabilization. Evaluate each structure's features, considering factors such as hyperconjugation and resonance, to make your determination.
Use the "Reset" button to start over if needed, and click "Help" for additional guidance.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F68716c71-3638-49ca-ac03-387df5fffe44%2Fbff4762e-a10e-42c8-8ced-e5336cf7ca77%2Fpcl93sn_processed.png&w=3840&q=75)
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