Rank the carbocations in the table below in order of increasing stability (1 least stable and 4 most stable). Give detailed Solution with explanation needed of all with structures don't give Handwritten answer + F F + + (Choose one) (Choose one) (Choose one) (Choose one) A
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![Rank the carbocations in the table below in order of increasing stability (1 least stable and 4 most stable).
Give detailed Solution with
explanation needed of all
with structures don't give
Handwritten answer
+
F F
+
+
(Choose one)
(Choose one)
(Choose one)
(Choose one)
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- Please don't provide handwritten solution....4. For the following reactions, develop a transition-state structure using molecular models which would account for the observed stereoselectivity. Also, describe the type of pericyclic reactions using the proper terminology. (each Br heat A & Br b) F 0°C F heat heat d) product? =& & MeO₂C OCH3 H HO 1. CO₂Me مر CO₂Me LOCH3 heat heat MeO₂C HODecide which carbocation in each pair is more stable
- Give me detailed Solution with explanation needed...don't give Handwritten answerQ4 Which statement below about Snl reactions is incorrect? (A) SNl reactions are stepwise and have intermediates. (B) The slow step in a Snl reaction is formation of the carbocation intermediate. (C) SNl reactions have first order kinetics which means only the alkyl halide is involved in the rate limiting step. (D) The products of a Syl reaction will be a pair of enantiomers. (E) An aprotic solvent is best for Snl reactions as they tend to help stabilize carbocation intermediates.(a) Rank the following carbocations in order of increasing electrophilicity (1 = lowest electrophilicity, 4 = highest electrophilicity). (b) Rank the following 1,1-halomethylcyclopentanes in order of reactivity in an SN1 reaction (1 = lowest reactivity, 4 = highest reactivity. CH3 CI B with SNI, nor reactive means more stable (c) Rank the following species in terms of increasing nucleophilicity in an SN2 reaction in a po aprotic solvent (1 = lowest nucleophilicity, 4 = highest nucleophilicity).
- G.115. I need all three sub parts .....Please show the mechanism with arrow formalism.Complete the following: Stereochemistry, enantio-, and regioselectivity are important. CrO3, H2SO4 a) OH Bromination of an alcohol (Sn2) type EtO₂C CO₂Et b) b) d) H3CO type NH2 a) b) H3CO type a) b) OH g) type CN CI h) acetone Swern Oxidation type type CO₂H type Доно i) Me3SICI, Imidazole OSiMe3 Et3N, CH2Cl2 Br type a) Mg°, THF Br j) b); H3O+ H2SO4 (H+) MeOH OMe type type
- Give the major organic product(s) of the following. Include stereochemistry when applicable. 1) Nal Br a) 2) NaCN, acetone 1) NaOC(CH3)3, heat d Br 2) BH₂ THF; 3) H,O,, NaOH(aq) b) c) d) c) 2) KOC(CH3)3, heat Copyright University of California Merced 2022 Br 1) NaOH, heat 2) MCPBA 1) KOC(CH3)3, heat 2) H3O+Please help with part A, B, C, D:7В. (2 Draw the structure of the product, substrate or condition in the following reactions (should clearly indicate the stereochemistry). (а) OH (b) OsO vaHSO3 (c) 1) (sia)2 BH 2) NaOH/H,O2 H20 (d) HBr (2 equiv) Br, Br Hint: This is the only product formed (e) Br Br2 H20 OH (f)
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