Question Completion Status: QUESTION 5 Which of the compounds below would exhibit the FEWEST chemically distinct hydrogens in the ¹H NMR spectrum? CH3 CH3 CH3 CH3 & 6.60 CH3 CH3 с A B D C CA B D CH₂CH3
Analyzing Infrared Spectra
The electromagnetic radiation or frequency is classified into radio-waves, micro-waves, infrared, visible, ultraviolet, X-rays and gamma rays. The infrared spectra emission refers to the portion between the visible and the microwave areas of electromagnetic spectrum. This spectral area is usually divided into three parts, near infrared (14,290 – 4000 cm-1), mid infrared (4000 – 400 cm-1), and far infrared (700 – 200 cm-1), respectively. The number set is the number of the wave (cm-1).
IR Spectrum Of Cyclohexanone
It is the analysis of the structure of cyclohexaone using IR data interpretation.
IR Spectrum Of Anisole
Interpretation of anisole using IR spectrum obtained from IR analysis.
IR Spectroscopy
Infrared (IR) or vibrational spectroscopy is a method used for analyzing the particle's vibratory transformations. This is one of the very popular spectroscopic approaches employed by inorganic as well as organic laboratories because it is helpful in evaluating and distinguishing the frameworks of the molecules. The infra-red spectroscopy process or procedure is carried out using a tool called an infrared spectrometer to obtain an infrared spectral (or spectrophotometer).
![**Question Completion Status:**
**QUESTION 5**
Which of the compounds below would exhibit the FEWEST chemically distinct hydrogens in the \( ^1H \) NMR spectrum?
\[ \text{(A)} \quad \text{Compound with two CH}_3 \text{ groups on a benzene ring in the 1,2-positions (ortho).} \]
\[ \text{(B)} \quad \text{Compound with two CH}_3 \text{ groups on a benzene ring in the 1,3-positions (meta).} \]
\[ \text{(C)} \quad \text{Compound with two CH}_3 \text{ groups on a benzene ring in the 1,4-positions (para).} \]
\[ \text{(D)} \quad \text{Compound with an ethyl (CH}_2\text{CH}_3\text{) group on a benzene ring.} \]
Options:
- B
- D
- C
- A](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ffe9fe32c-b492-41de-b627-5e5dec5bc081%2Fe2e42d84-878f-45f6-b5ae-da9ebed1ba90%2Fgey44mi_processed.jpeg&w=3840&q=75)
![**NMR Spectrum Analysis and Identification**
The proton NMR spectrum of a compound, \( \text{C}_3\text{H}_6\text{Cl}_2 \), is provided with the following characteristics:
- A pentet at \( \delta 2.19 \)
- A triplet at \( \delta 3.72 \)
- Integration ratio: 1:2
**Objective**: Determine which compound this data corresponds to from the options provided.
**Options**:
A) \( \text{CH}_3\text{CH}_2\text{CHCl}_2 \)
B) \( \text{ClCH}_2\text{CH}_2\text{CH}_2\text{Cl} \)
C) \( \text{CH}_2\text{CHClCH}_2\text{Cl} \)
D) \( \text{CH}_3\text{CH}_2\text{CH}_2\text{Cl} \)
The NMR spectrum shows:
- A tall peak (B) at \( \delta 3.75 \) corresponding to the triplet with relative area 2.00.
- A smaller peak (A) at \( \delta 2.20 \) corresponding to the pentet with relative area 1.00.
The separation between the peaks at \( \delta 3.72 \) and \( \delta 2.19 \) is about 90 Hz, which gives information on coupling constants and the proximity of interacting hydrogens.
**Graph Description**:
- **X-Axis**: Chemical shift in parts per million (ppm) ranging from 0 to 7.
- **Y-Axis**: Relative intensity.
- Peaks are marked with their respective chemical shifts and integration values.
- The graph includes a TMS marker indicating the 0 ppm reference point.
By analyzing the spectrum data and comparing it with possible molecular structures, the best match is **B) \( \text{ClCH}_2\text{CH}_2\text{CH}_2\text{Cl} \)** (1,3-dichloropropane), based on the integration and splitting pattern observed.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ffe9fe32c-b492-41de-b627-5e5dec5bc081%2Fe2e42d84-878f-45f6-b5ae-da9ebed1ba90%2Fq546gna_processed.jpeg&w=3840&q=75)
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