Question 9. Calcium carbonate is sparingly soluble in water. CACO) Caag) Co (a) K-34 10 (a) Caleulate the solubility of CaCO, in sea water containing 0.01 mol L of Ca ions

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Question 9.
Calcium carbonate is sparingly soluble in water.
CaCO() Cataq) CO (aq) K,-34 x 10
(a) Calculate the solubility of CaCO, in sea water containing 0.01 mol L of Ca" ions.
Given the additional information below and using the Henderson Hasselbalch equation,
what is the major form of carbonate in sea water and why?
(b)
pH sea water-8.1
H;CO, pKa =6.35
HCO, pka- 10.33
Write down the relevant equilibria and explain why the actual solubility of calcium
carbonate (4.6 x 10 mol L) is higher than the value you determined in part (a)?
(c)
Transcribed Image Text:Question 9. Calcium carbonate is sparingly soluble in water. CaCO() Cataq) CO (aq) K,-34 x 10 (a) Calculate the solubility of CaCO, in sea water containing 0.01 mol L of Ca" ions. Given the additional information below and using the Henderson Hasselbalch equation, what is the major form of carbonate in sea water and why? (b) pH sea water-8.1 H;CO, pKa =6.35 HCO, pka- 10.33 Write down the relevant equilibria and explain why the actual solubility of calcium carbonate (4.6 x 10 mol L) is higher than the value you determined in part (a)? (c)
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