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Question 5: Indicate the stereochemistry at each chiral center - OH но - он : SH HO. H :ÖH : OH Br. H. :

Question 5: Indicate the stereochemistry at each chiral center - OH но - он : SH HO. H :ÖH : OH Br. H. :

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Question 5: Indicate the stereochemistry at each chiral center** The image contains three chemical structures, each with chiral centers that require stereochemical notation. 1. **First Structure:** - A carbon chain with several functional groups: - A top carbon is bonded to a hydroxyl group (OH) and a hydrogen atom (H). - The middle carbon is connected to two hydroxyl groups (OH) on opposite sides. - The bottom carbon also has a hydroxyl group attached. - Stereochemistry needs to be indicated at each chiral center (marked with bonds going out of the plane). 2. **Second Structure:** - A cyclohexane ring with substituents: - A hydroxyl group (OH) is on one side. - There is an oxygen atom connected to the ring by a single bond. - A thiol group (SH) and a chlorine atom (Cl) are also attached at different positions. - Indicate stereochemistry at the chiral centers, which involve atoms coming in and out of the plane. 3. **Third Structure:** - A bicyclic structure: - Contains a bridgehead carbon attached to a hydroxyl group (OH) and a bromine atom (Br). - There is also a double-bonded oxygen atom present. - Identify chiral centers and note their stereochemistry. In each case, the task is to assign R/S configuration at each chiral center of the molecules presented.
Transcribed Image Text:**Question 5: Indicate the stereochemistry at each chiral center** The image contains three chemical structures, each with chiral centers that require stereochemical notation. 1. **First Structure:** - A carbon chain with several functional groups: - A top carbon is bonded to a hydroxyl group (OH) and a hydrogen atom (H). - The middle carbon is connected to two hydroxyl groups (OH) on opposite sides. - The bottom carbon also has a hydroxyl group attached. - Stereochemistry needs to be indicated at each chiral center (marked with bonds going out of the plane). 2. **Second Structure:** - A cyclohexane ring with substituents: - A hydroxyl group (OH) is on one side. - There is an oxygen atom connected to the ring by a single bond. - A thiol group (SH) and a chlorine atom (Cl) are also attached at different positions. - Indicate stereochemistry at the chiral centers, which involve atoms coming in and out of the plane. 3. **Third Structure:** - A bicyclic structure: - Contains a bridgehead carbon attached to a hydroxyl group (OH) and a bromine atom (Br). - There is also a double-bonded oxygen atom present. - Identify chiral centers and note their stereochemistry. In each case, the task is to assign R/S configuration at each chiral center of the molecules presented.
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