Question 3. Complete the following redox reaction, where X is H20, NCS, SCN', and I. [Co(NH3)sX]2* + [Cr(H20)s]?* → ? Answer the following questions: (a) propose the reaction mechanism, (b) suggest the order of the rate of reaction, and (c) explain the variation in the rate of reaction.

Q: Name each of the compounds or ions given. (a) [Co(en)2(NO2)Cl]+(b) [Co(en)2Cl2]+(c) [Pt(NH3)2Cl4](d)…

A: Given compounds and ions    (a) [Co(en)2(NO2)Cl]+   (b) [Co(en)2Cl2]+   (c) [Pt(NH3)2Cl4]   (d)…

Q: (a) Consider the following two Fe complex ions: Complex A - [Fe(H2O)3(OH)3]  and  Complex B…

A: (i) The d-electronic configuration of A and B are given below: For    , the oxidation state of Iron…

Q: Suppose you prepared [Co(en)2Cl2]+. How many isomers, geometric and optical, could be formed?…

A: The complex given is [Co(en)2Cl2]+.

Q: Write down the d-electron count of [Fe(H2O)6]3+ and [Fe(CN)6]4-, from this guess which one will have…

A: Let us discuss its complex and splitting.

Q: 3. Assuming that each of the following compounds contains an octahedral complex ion, which compound…

A: (A) Co(NH3)Cl3

Q: What will the yield of silver chloride, AgCl, be if. Two moles of each of the following compounds…

A: Here the compound (a) has 2 chlorine atoms in the ionisation sphere so the 2 chlorine atoms react…

Q: Chromium forms two common anionic carbonyl compounds: [Cr(CO)5]n- and [Cr(CO)4]m-. Deduce the…

A: The coordination compounds follows the EAN rule. To find the charge, first of all find the number of…

Q: How many ligands are present in [Co(NH3)4Cl2)]Cl?

A: A ligand represents an ion as well as molecule  that connects to central metal atom to establish a…

Q: The complex ion [Co(H2O)6]3+ exhibits absorbance with max = 600 nm (orange region) , while…

A: (a) When a compound absorbs energy in the visible range, the electronic transitions takes place from…

Q: In acidic aqueous solution, the purple complex ion Co(NH3)5Br2+  undergoes a slow reaction in which…

A: Given,Initial concentration of Co(NH3)5 Br2+ = 0.100 Mrate constant = 6.3×10−6 s-1the molarity of…

Q: Draw the diastereoisomers and optical isomers of  [Co(NH₃)₂(H₂O)₂Cl₂]⁺. Label which are…

A: In the compound given as, [Co(NH₃)₂(H₂O)₂Cl₂]⁺ The coordination number of central metal ion is 6.…

Q: An equilibrium of [Cu(H2O)6 ]2+ [Cu(NH3)4(H2O)2]2+ Would the complexes have the same max wavelength…

A: In the Cu2+ (d9) complexes, the eq orbitals are asymmetrically filled. The color of the complexes is…

Q: Give the number of d electrons (n of dn) for the central metal ion in (a) [Cr(H2O)6](ClO3)2; (b)…

A: Electronic configuration is used to describe how the electrons of an atom/ion are distributed in the…

Q: Calculate the percentage of covalent chloride in the complex [Co(NH3)5Cl]Cl2, given that the molar…

A: Given complex is : [Co(NH3)5Cl]Cl2  Molar mass of [Co(NH3)5Cl]Cl2 = 233.4 g/mol  Atomic mass of Cl =…

Q: Give the proper name for each of the following compounds: (a) Pt(NH3)2Cl2 (b) [Rh(NH3)5Cl]Cl2 (c)…

A: since you have posted a question with multiple subparts, we are entitiled to answer answer only…

Q: The reaction between OH- and which of the following complexes could be made to occur faster (or be…

A:

Q: The spectrochemical series is I< Br¯< Cl <F< OH<H2O<NH3 < en< NO2 < CN Which of the following…

A: The complex having higher C.F.S.E. will absorb radiation of higher energy.

Q: 3. Consider the blue-colored compound, [Cr(H₂O)]3³ and the yellow-colored compound, [Cr(CN)6]³.…

A: The given questions can be explained as:

Q: Determine the coordination number (c.n.) and the oxidation state (o.s.) of the transition metal in…

A: Since you have posted a question with multiple sub parts, we will solve first three sub parts for…

Q: Draw the structures of isomers, if any, and write the names of the following complexes: (i)…

A: Isomers are compounds having the same molecular formula but different structural arrangements.…

Q: Determine the oxidation state and coordination number of [Cr(H2O)6]3+, [Co(NH3)3Cl3]-, & [Cu(CN)4]2-

A: The oxidation state and coordination number of given complexes has to be determined.

Q: Cobalt (II) chloride can form two complexes when dissolved in water

A: 1. Actually Cobalt (II) chloride exist as CoCl2.6H2O(hydrated form),when it dissolved in water it…

Q: Which of the following compounds can exhibit cis-trans isomerism? O [Fe(CO)2(NH3)2]²* O [Zn(CO)5Br]*…

A: Suitably substituted square planar and octahedral complexes can show the cis-trans isomerism.…

Q: in which transition are these complexes: 1:[Co(NH3)4CO3]NO3 2:[Co(NH3 )5Cl]Cl2…

A: Co(III) Complexes with Ligands

Q: Co(H2O)6]2+ (aq) + 4 Cl-(aq )⇆ [CoCl4]2-(aq) + 6 H2O    3. Does the value of the equilibrium…

A: Equilibrium constant is defined as the ratio of partial pressure of products to the partial pressure…

Q: Which compound do you expect to absorb the highest energy photon? [Co(H2O)6]3+ [Co(NH3)6]3+…

A: In coordination compounds, the more the value of ∆ο, the more the high-energy photon absorbed.…

Q: Of the following complex ions, the one with probably the highest formation constant will be: (a)…

A: Given complexes,              a. [Co(en)3]3+(en represents ethylenediamine)              b.…

Q: Find the number of unpaired electrons, magnetic moment and crystal field stability energy for each…

A: We are given with seven compounds and we have to calculate no. of unpaired electrons, magnetic…

Q: Name the following compounds and draw their structures: (5) a) [Fe(OH)( H2O)5] Cl2 b) Li[Cr(OH)4] c)…

A: The objective of the question is to name the given compounds and draw their structures. The…

Q: Draw the structures of the stereoisomers possible for [Co(NH3)4Cl2]Cl complex synthesized by Alfred…

A:

Q: c) Draw the structure of each of the following complexes. Clearly show the geometry at the central…

A: Here we have to draw the structure of each metal complexes and the geometry of central metal ion- A…

Q: Coordination Number (explain reasoning  create a model of the cation, and draw its projection…

A: Geometric isomers are two or more coordination compounds which contain the same number and types of…

Q: Consider the following complexes: [FeCl6]3- and [Fe(CN)6]3-, which possess very different magnetic…

A:

Q: [CoC((NO2)(NH3)J[PtCla(NH3)] 1. What is the oxidation number of Pt? 2. What are the respective…

A: We are authorised to solve first three subparts of a question. Please post to rest of the sub parts…

Q: Assign a following chemical compounds. Compound Name (a) Na[Mn(CN)5] fill in the blank 1 (b)…

A: Here we have to write systematic names of the following co-ordinate compounds.

Q: How would you draw the isomer structure(s) for [Cr(en)2BrCl] 1+

A: Since, Isomer are those whose molecular formula same but structural formula is different. Thus,

Q: Equation 20: [COC14]2-(alc,blue) + 6H2O(1,colorless) = [Co(H2O)6]?*(aq.pink) + 4CI-(aq.colorless)

A: The ions which don't participate in chemical reaction at all directly are called spectator ions.…

Q: Identify each of the following pairs of coordination compounds as coordination isomers, linkage…

A: Since you are asked for multiple sub-parts, we are entitled to solve first three only.

Q: If a solution known to be made up of an octahedral cobalt complex ion [Co(NH3)6]3+ appears orange to…

A: [Co(NH3)6]3+ is an octahedral complex with six ammonia ligands. Cobalt has the atomic number 27,…

Q: Depict and explain the Crystal field stabilization theory based on the color the below complexes.…

A:

Q: Which is more acidic and why?  [Fe(H2O)6]2+ or [Fe(NH3)(H2O)5]2+

A: Acidity: It basically describes the how much amount of acid present in given compound. Acid: Species…

Q: Write the hybridization, shape and magnetic character of [Fe(CN)6]4-.

A:

Q: (b) When NH3 is added to aqueous CuSO4, the complex [Cu(OH2)2(NH3)4]*+ is ultimately formed.…

A: When NH3 is added to aqueous CuSO4, the complex [Cu(OH)2(NH3 )4]2+ is ultimately formed. Initially,…

Q: Determine if each of the following complexes exhibits geometric isomerism. If geometric isomers…

A: solution- Geometric isomers-the coordinate compounds that have the same number and the same type of…

Q: CoF6]3- absorbs 700 nm (red) radiation whereas [Co(H2O)6]3+ absorbs 600 nm (orange) radiation. Draw…

A:

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.