In acidic aqueous solution, the purple complex ion Co(NH3)5Br2+ undergoes a slow reaction in which the bromide ion is replaced by a water molecule, yielding the pinkish-orange complex ion : Co(NH3)5(H2O)3+ Co(NH3)5Br2+Purple(aq)+H2O(l) → Co(NH3)5(H2O)3+Pinkish−orange(aq)+Br−(aq) The reaction is first order in Co(NH3)5Br2+, the rate constant at 25 ∘C is 6.3×10−6 s−1, and the initial concentration of Co(NH3)5Br2+ is 0.100 MM. What is its molarity after a reaction time of 19.0 h ? How many hours are required for 85 %% of the Co(NH3)5Br2+ to react?
Atomic Structure
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Shape of the D Orbital
Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.
In acidic aqueous solution, the purple complex ion Co(NH3)5Br2+ undergoes a slow reaction in which the bromide ion is replaced by a water molecule, yielding the pinkish-orange complex ion : Co(NH3)5(H2O)3+
Co(NH3)5Br2+Purple(aq)+H2O(l) → Co(NH3)5(H2O)3+Pinkish−orange(aq)+Br−(aq)
The reaction is first order in Co(NH3)5Br2+, the rate constant at 25 ∘C is 6.3×10−6 s−1, and the initial concentration of Co(NH3)5Br2+ is 0.100 MM.
What is its molarity after a reaction time of 19.0 h ?
How many hours are required for 85 %% of the Co(NH3)5Br2+ to react?
Given,
Initial concentration of Co(NH3)5 Br2+ = 0.100 M
rate constant = 6.3×10−6 s-1
the molarity of Co(NH3)5 Br2+ after a reaction time of 19.0 h is:
the time ( in hours) are required for 85 % of the Co(NH3)5 Br2+ to react is:
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