Question 2 The molar heat capacity of a sample of gas at constant-pressure varies with temperature according to the following equation, Cp.m (J. K¯¹) = a + bT+¶µ²- Calculate the change in enthalpy of NO(g) when the temperature is raised from 25°C to 350°C. Question 3 CO2(g) is heated from 25°C to 500°C. Calculate the molar enthalpy of formation for CO2(g), as a real gas, for this heating process. Question 4 The density of CO2 is experimentally determined as being 44.0 g.L-1 at 5 atm and 27 °C. (i) Calculate the value of the molar volume, Vm. (ii) Calculate the value of the compression factor, Z, at 27 °C. (iii) What can you deduct from the value of Z?

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Question 2
The molar heat capacity of a sample of gas at constant-pressure varies with
temperature according to the following equation, Cpm (J.K-¹) = a + bT+T².
Calculate the change in enthalpy of NO(g) when the temperature is raised from
25°C to 350°C.
Question 3
CO2(g) is heated from 25°C to 500°C. Calculate the molar enthalpy of formation
for CO2(g), as a real gas, for this heating process.
Question 4
The density of CO2 is experimentally determined as being 44.0 g.L-¹ at 5 atm
and 27 °C.
(i) Calculate the value of the molar volume, Vm.
(ii) Calculate the value of the compression factor, Z, at 27 °C.
(iii) What can you deduct from the value of Z?
Transcribed Image Text:Question 2 The molar heat capacity of a sample of gas at constant-pressure varies with temperature according to the following equation, Cpm (J.K-¹) = a + bT+T². Calculate the change in enthalpy of NO(g) when the temperature is raised from 25°C to 350°C. Question 3 CO2(g) is heated from 25°C to 500°C. Calculate the molar enthalpy of formation for CO2(g), as a real gas, for this heating process. Question 4 The density of CO2 is experimentally determined as being 44.0 g.L-¹ at 5 atm and 27 °C. (i) Calculate the value of the molar volume, Vm. (ii) Calculate the value of the compression factor, Z, at 27 °C. (iii) What can you deduct from the value of Z?
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