QUESTION 12 What diene and dienophiles are used to make the following compounds? of b.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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What diene and dienophiles are used to make the following compounds?

**Question 12**

*What diene and dienophiles are used to make the following compounds?*

**a.** The structure on the left features a bicyclic compound with a six-membered ring containing a double bond and attached to a five-membered ring with a ketone group (C=O) extending from the ring.

**b.** The structure on the right shows a bicyclic compound with a six-membered ring containing a double bond and a five-membered lactone ring (cyclic ester) attached, which has two ketone groups. The rings share two carbon atoms, forming a bridgehead structure.
Transcribed Image Text:**Question 12** *What diene and dienophiles are used to make the following compounds?* **a.** The structure on the left features a bicyclic compound with a six-membered ring containing a double bond and attached to a five-membered ring with a ketone group (C=O) extending from the ring. **b.** The structure on the right shows a bicyclic compound with a six-membered ring containing a double bond and a five-membered lactone ring (cyclic ester) attached, which has two ketone groups. The rings share two carbon atoms, forming a bridgehead structure.
Expert Solution
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We can find out diene and dienophile by doing retro Diels-Alder reaction. 

 

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