QUESTION 10 How many times do the reaction rates change if the concentrations of reactants are changed according to the following description: CH₂OH CH₂CH₂ Br A + CHO B CH3 H₂C-C-Br + CH₂ A CH₂OH B CH₂CH₂-OCH₂ CH3 H₂C-C -OCH₂ CH3 In the first reaction, both concentrations of A and B are increased twice, the reaction rate changes times In the second reaction, both concentrations of A and B are increased three times, the reaction rate changes times Hint: Identify if the reaction is SN1 or SN2. SN1 reaction is first order, and reaction rate is proportional to the substrate concentration only rak(A); SN2 is second order, reaction rate is proportional to both the substrate and the nucleophile concentrations rak(A)(B). r- reaction rate; k-rate constant; (A)-concentration of substrate; (B)- concentration of nucleophile.

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QUESTION 10
How many times do the reaction rates change if the concentrations of reactants are changed according to the
following description:
CH₂OH
CH₂CH₂ Br
A
+ CH3O
B
CH3
H₂C-C-Br +
CH3
CH₂OH
CH₂CH₂-OCH3
CH3
H₂C-C -OCH₂
CH3
In the first reaction, both concentrations of A and B are increased twice, the reaction rate changes
times
In the second reaction, both concentrations of A and B are increased three times, the reaction rate changes
times
Hint: Identify if the reaction is SN1 or SN2. SN1 reaction is first order, and reaction rate is proportional to the
substrate concentration only r-k(A); SN2 is second order, reaction rate is proportional to both the substrate and the
nucleophile concentrations r-k(A)(B). r- reaction rate; k-rate constant; (A)-concentration of substrate; (B)-
concentration of nucleophile.
Transcribed Image Text:QUESTION 10 How many times do the reaction rates change if the concentrations of reactants are changed according to the following description: CH₂OH CH₂CH₂ Br A + CH3O B CH3 H₂C-C-Br + CH3 CH₂OH CH₂CH₂-OCH3 CH3 H₂C-C -OCH₂ CH3 In the first reaction, both concentrations of A and B are increased twice, the reaction rate changes times In the second reaction, both concentrations of A and B are increased three times, the reaction rate changes times Hint: Identify if the reaction is SN1 or SN2. SN1 reaction is first order, and reaction rate is proportional to the substrate concentration only r-k(A); SN2 is second order, reaction rate is proportional to both the substrate and the nucleophile concentrations r-k(A)(B). r- reaction rate; k-rate constant; (A)-concentration of substrate; (B)- concentration of nucleophile.
QUESTION 13
Tell whether the following reaction will be SN1. SN2, E1, or E2 (Textbook Worked Example 11-5 and problem 11-20):
K* OC(CH3)3
(CH3)3COH, 80°C
CH3
H₂C-C-CI
CH3
CH₂CH3
H₂C-C-Br
CH3
> > > >
Br
<<<<
ABCO
Br
CH₂CH₂OH
25°C
CH₂OH
80°C
K* CN
DMF, 0°C
CH3
H₂C-C-OCH₂CH3
CH3
H₂C-C=C-CH3
CH3
CN
A E2
B. SN2
C. SN1
D.E1
A
B
D
Transcribed Image Text:QUESTION 13 Tell whether the following reaction will be SN1. SN2, E1, or E2 (Textbook Worked Example 11-5 and problem 11-20): K* OC(CH3)3 (CH3)3COH, 80°C CH3 H₂C-C-CI CH3 CH₂CH3 H₂C-C-Br CH3 > > > > Br <<<< ABCO Br CH₂CH₂OH 25°C CH₂OH 80°C K* CN DMF, 0°C CH3 H₂C-C-OCH₂CH3 CH3 H₂C-C=C-CH3 CH3 CN A E2 B. SN2 C. SN1 D.E1 A B D
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