Question 1 Draw the structure of the complex below. Please explain the steps of how to you determine the oxidation states and coordination numbers of each metal centre. Bis[bis(trimethylphosphine)gold(I)]  [tetrahydroxopalladate(II)] Bis(biphenyl)ruthenate(II)-u-dichloro-di(phenylpyridine)osmate(II) ion

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Question 1

Draw the structure of the complex below. Please explain the steps of how to you determine the oxidation states and coordination numbers of each metal centre.

  1. Bis[bis(trimethylphosphine)gold(I)]  [tetrahydroxopalladate(II)]
  2. Bis(biphenyl)ruthenate(II)-u-dichloro-di(phenylpyridine)osmate(II) ion

Question 2

Show the calculation of effective atomic number (EAN) for the complex below. Please explain the oxidation state of the metal centre below .

  1. Bis(ethylenediamine)cupper(II) bis[di(acetylacetonato)rhodate(I)]
  2. Bis(bipyridine)rhodium(III)-u-dioxo-di(oxalato)chromate(0) ion

Question 3

  1. Propose a synthetic pathway forcis-[NiCl2(CO)2] usingtrans-effect.
  2. Propose the methods to differentiate the isomers in between [RhCl2(H2O)4]Cl and [RhCl3(H2O)3].H2O.

Question 4

Draw the hybridization for the metal centre of the complex below. You need to determine the geometry before you start,

  1. [RhMe(PPh3)3]
  2. [RhMe(PMe3)4

Question 5

Determine the hybridization of the metal centre in the complexes below using Ligand Field Theory.

  1. [RhCl3(OH)3]3-
  2. [Cr(en)2(PMe3)2]

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