Q4. The following is the ¹3C NMR spectrum of a highly concentrated solution of dicyclopentadiene obtained in chloroform-d. Despite the high purity of the compound based on ¹H NMR, there is a massive peak observed at 77.2 ppm in this 13C spectrum, which doesn't correspond to any resonances expected for dicyclopentadiene. What is this peak, and why do you not see a corresponding peak for this compound in your ¹H NMR spectrum? <-136.22 132.62 222E- 132.23 135 130 125 120 115 110 105 100 95 85 80 75 70 65 60 10'55- · 55 <-50.56 50 45 40 35 wwwww 30

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Q4. The following is the 13C NMR spectrum of a highly concentrated solution of dicyclopentadiene
obtained in chloroform-d. Despite the high purity of the compound based on ¹H NMR, there is a massive
peak observed at 77.2 ppm in this 13C spectrum, which doesn't correspond to any resonances expected
for dicyclopentadiene. What is this peak, and why do you not see a corresponding peak for this compound
in your ¹H NMR spectrum?
79-751
<-136.22
-132.62
132.27
132.23
135 130
125
120
115
110
105
100
95
90
85
80
75
70
65
60
55
50
45
40
35
30
Transcribed Image Text:Q4. The following is the 13C NMR spectrum of a highly concentrated solution of dicyclopentadiene obtained in chloroform-d. Despite the high purity of the compound based on ¹H NMR, there is a massive peak observed at 77.2 ppm in this 13C spectrum, which doesn't correspond to any resonances expected for dicyclopentadiene. What is this peak, and why do you not see a corresponding peak for this compound in your ¹H NMR spectrum? 79-751 <-136.22 -132.62 132.27 132.23 135 130 125 120 115 110 105 100 95 90 85 80 75 70 65 60 55 50 45 40 35 30
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