Answered: Q22: If you rotate the hydrogen atoms…

Q22: If you rotate the hydrogen atoms to a different position in a model of C2H5Cl by turning about the central C—C bond, do you get different structural (or constitutional) isomers of C2H5Cl?

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter6: Covalent Bonding

Section: Chapter Questions

Problem 28QRT

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Question

Q22: If you rotate the hydrogen atoms to a different position in

a model of C₂H₅Cl

by turning about the central C—C bond, do you get different structural (or constitutional) isomers of C₂H₅Cl?

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These two different C2H6O compounds are called structural (or constitutional) isomers - compounds with the same molecular formula but with different connections among their constituent atoms. If you must break and make new bonds in order to convert one structure into the other (not simply rotate the model around), then they are structural isomers. The concept of isomers is very important in organic chemistry and biochemistry. This is also another instance where condensed formulas can be very useful because they can help you distinguish two isomers apart even when you don't have models. Exercise 8) Can your models be interconverted by rotating bonds, or must the bonds be broken first? What does that mean about these two structures?
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