Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Provide the Major product for the following addition reactions

Transcribed Image Text:### Chemical Reactions of Alkenes
This image displays three distinct alkene reactions, showcasing different reagents and conditions leading to various products.
1. **Reaction with HBr and Peroxide (ROOR)**
- **Reactant:** An alkene with the structure CH₃-CH(CH₃)-CH=CH₂.
- **Reagents:** Hydrogen bromide (HBr) and a peroxide, often abbreviated as ROOR.
- **Description:** This reaction represents the anti-Markovnikov addition of HBr to the alkene. The presence of peroxide initiates a radical mechanism, resulting in the bromine atom adding to the less substituted carbon of the double bond.
2. **Reaction with Bromine (Br₂)**
- **Reactant:** The same alkene, CH₃-CH(CH₃)-CH=CH₂.
- **Reagent:** Bromine (Br₂).
- **Description:** When alkenes are treated with Br₂, bromine adds across the double bond in an anti-addition fashion, forming a vicinal dibromide. The reaction is typically conducted in an inert solvent like dichloromethane.
3. **Reaction with Hydronium Ion (H₃O⁺)**
- **Reactant:** A cyclohexene structure with a single double bond (C₆H₁₀).
- **Reagent:** Hydronium ion (H₃O⁺).
- **Description:** This reaction involves the acid-catalyzed hydration of the alkene, where water adds across the double bond. This reaction follows Markovnikov's rule, resulting in the formation of an alcohol. The hydronium ion serves as a catalyst, promoting the reaction through a carbocation intermediate.
These reactions are fundamental to understanding electrophilic addition mechanisms in organic chemistry, demonstrating how different reagents influence the regioselectivity and stereochemistry of addition to alkenes.
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