Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Title: Understanding IUPAC Nomenclature with Skeletal Structures**
**Objective: Learn to provide the correct IUPAC name for skeletal (line-bond) structures.**
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**Task: Identify the IUPAC name for the given skeletal structure.**
*Description of Structure:*
The image showcases a skeletal structure common in organic chemistry. The line-bond structure consists of a main chain with three carbon atoms. Each vertex and endpoint in the structure represents a carbon atom, in line with the conventions of skeletal structures where hydrogen atoms are not depicted explicitly.
**Analysis:**
1. **Main Carbon Chain**:
- The longest continuous chain consists of three carbon atoms, indicating propane as the base name. However, observe carefully, the longest chain could potentially be extended if considering branches.
2. **Substituents**:
- Two methyl groups are attached to the middle carbon (second position).
- Another methyl group is attached to the third carbon in the longest chain.
**Correct IUPAC Name:**
- The compound is named 2,3,3-trimethylpentane due to:
- The longest carbon chain actually being five carbons long ("pentane").
- Three methyl groups attached at the 2nd and 4th positions of the longest chain.
This name corrects the initial suggestion given as "2,4-tetrapentane," which is not a valid name under IUPAC standards, as "tetra" refers to a quadruple substitution that doesn't match the structure presented.
*Remember*, accurately identifying the longest carbon chain and correctly numbering it to provide the smallest possible numbers for substituents is essential in determining the correct IUPAC name.
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This exercise illustrates the importance of applying systematic IUPAC naming rules to effectively communicate molecular structures in chemistry.
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