Prove the following commutator identity: [AB, C] = A[B. C]+[A. C]B.
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- please answer c) only 2. a) A spinless particle, mass m, is confined to a two-dimensional box of length L. The stationary Schrödinger equation is - +a) v(x, y) = Ev(x, y), for 0 < r, y < L. The bound- ary conditions on ý are that it vanishes at the edges of the box. Verify that solutions are given by 2 v(1, y) sin L where n., ny = 1,2..., and find the corresponding energy. Let L and m be such that h'n?/(2mL²) = 1 eV. How many states of the system have energies between 9 eV and 24 eV? b) We now consider a macroscopic box (L of order cm) so that h'n?/(2mL?) ~ 10-20 eV. If we define the wave vector k as ("", ""), show that the density of states g(k), defined such that the number of states with |k| between k and k +dk is given by g(k)dk, is Ak 9(k) = 27 c) Use the expression for g(k) to show that at room temperature the partition function for the translational energy of a particle in a macroscopic 2-dimensional box is Z1 = Aoq, where 2/3 oq = ng = mk„T/2nh?. Hence show that the average…O Consider the kinetic energy matrix elements between Hydrogen states (n' = 4, l', m'| |P|²| m -|n = 3, l, m), = for all the allowed l', m', l, m values. What kind of operator is the the kinetic energy (scalar or vector)? Use this to determine the following. For what choices of the four quantum numbers (l', m', l, m) can the matrix elements be nonzero (e.g. (l', m', l, m) (0, 0, 0, 0),...)? Which of these nonzero values can be related to each other (i.e. if you knew one of them, you could predict the other)? In this sense, how many independent nonzero matrix elements are there? (Note: there is no need to calculate any of these matrix elements.)Legrende polynomials The amplitude of a stray wave is defined by: SO) =x (21+ 1) exp li8,] sen 8, P(cos 8). INO Here e is the scattering angle, / is the angular momentum and 6, is the phase shift produced by the central potential that performs the scattering. The total cross section is: Show that: 'É4+ 1)sen² 8, .
- Consider the matrix representation of Lx, Ly and L₂ for the case l = 1 (see Matrix Representation of Operators class notes pp. 11-12). (a) Construct the matrix representation of L² for l = 1. (b) What are the eigenvalues and corresponding eigenvectors of L²? (c) Are the eigenvectors of L² the same as those of L₂? Explain. (d) Compute L² |x; +1), where |x;+1) is the eigenvector of La corresponding to eigenvalue +ħ.Evaluate the commutator [Â,B̂] of the following operators.