Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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a) Propose structures for compounds of the following molecular formulas, using the spectra given below.Show your work
![**Chemical Structure Analysis: NMR Spectra**
**Compound: C₁₁H₁₀O₂**
**¹H NMR Spectrum:**
- The horizontal axis represents the chemical shift in parts per million (ppm).
- Notable peaks are observed:
- Around 7.2 ppm, there is a single peak labeled as "2," indicating the presence of two hydrogen atoms in that environment.
- A cluster of peaks around 6.9 ppm labeled "11," indicating the presence of 11 hydrogen atoms.
- Peaks at approximately 2.5, 2.2, and 1.0 ppm, each labeled "2," suggesting that there are two hydrogen atoms contributing to each signal.
**¹³C NMR Spectrum:**
- The lower spectrum displays the ¹³C NMR results with chemical shifts ranging from 0 to 200 ppm.
- Peaks can be found around 150, 125, and 50 ppm, likely corresponding to different carbon environments within the molecule.
- The positioning and intensity of these peaks indicate the varying environments of carbon atoms in the molecular structure.
**Graph Explanation:**
- Each peak in the NMR spectra corresponds to a unique hydrogen or carbon environment in the molecule. The number of hydrogen or carbon atoms contributing to each signal helps in deducing the molecular structure.
- Chemical shift values and the number of contributing atoms provide insights into the electronic environments and interactions affecting the nuclei, helping to identify functional groups and structural features.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fe0440bae-aaea-4b30-a6d7-59f732dd66dd%2Fae141c4a-b4f8-4aa4-b873-30719db9cbb0%2Fm7445xd_processed.png&w=3840&q=75)
Transcribed Image Text:**Chemical Structure Analysis: NMR Spectra**
**Compound: C₁₁H₁₀O₂**
**¹H NMR Spectrum:**
- The horizontal axis represents the chemical shift in parts per million (ppm).
- Notable peaks are observed:
- Around 7.2 ppm, there is a single peak labeled as "2," indicating the presence of two hydrogen atoms in that environment.
- A cluster of peaks around 6.9 ppm labeled "11," indicating the presence of 11 hydrogen atoms.
- Peaks at approximately 2.5, 2.2, and 1.0 ppm, each labeled "2," suggesting that there are two hydrogen atoms contributing to each signal.
**¹³C NMR Spectrum:**
- The lower spectrum displays the ¹³C NMR results with chemical shifts ranging from 0 to 200 ppm.
- Peaks can be found around 150, 125, and 50 ppm, likely corresponding to different carbon environments within the molecule.
- The positioning and intensity of these peaks indicate the varying environments of carbon atoms in the molecular structure.
**Graph Explanation:**
- Each peak in the NMR spectra corresponds to a unique hydrogen or carbon environment in the molecule. The number of hydrogen or carbon atoms contributing to each signal helps in deducing the molecular structure.
- Chemical shift values and the number of contributing atoms provide insights into the electronic environments and interactions affecting the nuclei, helping to identify functional groups and structural features.
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