Organic Chemistry 8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
1 Covalent Bonding And Shapes Of Molecules 2 Alkanes And Cycloalkanes 3 Stereoisomerism And Chirality 4 Acids And Bases 5 Alkenes: Bonding, Nomenclature, And Properties 6 Reactions Of Alkenes 7 Alkynes 8 Haloalkanes, Halogenation, And Radical Reactions 9 Nucleophilic Substitution And Β-elimination 10 Alcohols 11 Ethers, Epoxides, And Sulfides 12 Infrared Spectroscopy 13 Nuclear Magnetic Resonance Spectroscopy 14 Mass Spectrometry 15 An Introduction To Organometallic Compounds 16 Aldehydes And Ketones 17 Carboxylic Acids 18 Functional Derivatives Of Carboxylic Acids 19 Enolate Anions And Enamines 20 Dienes, Conjugated Systems, And Pericyclic Reactions 21 Benzene And The Concept Of Aromaticity 22 Reactions Of Benzene And Its Derivatives 23 Amines 24 Catalytic Carbon-carbon Bond Formation 25 Carbohydrates 26 Lipids 27 Amino Acids And Proteins 28 Nucleic Acids 29 Organic Polymer Chemistry Chapter11: Ethers, Epoxides, And Sulfides
11.1 Structure Of Ethers 11.2 Nomenclature Of Ethers 11.3 Physical Properties Of Ethers 11.4 Preparation Of Ethers 11.5 Reactions Of Ethers 11.6 Silyl Ethers As Protecting Groups 11.7 Epoxides: Structure And Nomenclature 11.8 Synthesis Of Epoxides 11.9 Reactions Of Epoxides 11.10 Ethylene Oxide And Epichlorohydrin: Building Blocks In Organic Synthesis 11.11 Crown Ethers 11.12 Sulfides Chapter Questions Section: Chapter Questions
Problem 11.10P: Write names for these compounds. Where possible, write both IUPAC names and common names. Problem 11.11P Problem 11.12P: Each compound given in this problem is a common organic solvent. From each pair of compounds, select... Problem 11.13P: Account for the fact that tetrahydrofuran (THF) is very soluble in water, whereas the solubility of... Problem 11.14P Problem 11.15P: Write equations to show a combination of reactants to prepare each ether. Which ethers can be... Problem 11.16P: Propose a mechanism for this reaction. Problem 11.17P Problem 11.18P Problem 11.19P Problem 11.20P Problem 11.21P: Ethylene oxide is the starting material for the synthesis of 1,4-dioxane. Propose a mechanism for... Problem 11.22P Problem 11.23P: Predict the structural formula of the major product of the reaction of 2,2,3-trimethyloxirane with... Problem 11.24P: The following equation shows the reaction of trans-2,3-diphenyloxirane with hydrogen chloride in... Problem 11.25P: Propose a mechanism to account for this rearrangement. Problem 11.26P: Acid-catalyzed hydrolysis of the following epoxide gives a trans diol. Of the two possible trans... Problem 11.27P Problem 11.28P Problem 11.29P Problem 11.30P: Propose a mechanism for the following acid-catalyzed rearrangement. Problem 11.31P: Show reagents and experimental conditions to synthesize the following compounds from 1-propanol (any... Problem 11.32P: Starting with cis-3-hexene, show how to prepare the following diols. (a) Meso 3,4-hexanediol (b)... Problem 11.33P: Show reagents to convert cycloheptene to each of the following compounds. Problem 11.34P: Show reagents to convert bromocyclopentane to each of the following compounds. Problem 11.35P Problem 11.36P: Starting with acetylene and ethylene oxide as the only sources of carbon atoms, show how to prepare... Problem 11.37P: Following are the steps in the industrial synthesis of glycerin. Provide structures for all... Problem 11.38P Problem 11.39P Problem 11.41P: Aldehydes and ketones react with one molecule of an alcohol to form compounds called hemiacetals, in... Problem 11.42P Problem 11.43P: Write the products of the following sequences of reactions. Refer to your reaction roadmap to see... Problem 11.44P: Using your reaction roadmap as a guide, show how to convert 1-butene into dibutyl ether. You must... Problem 11.45P: Using your reaction roadmap as a guide, show how to convert cyclohexanol into racemic... Problem 11.46P: Using your reaction roadmap as a guide, show how to convert 1-butanol and ethanol into racemic... Problem 11.47P: During the synthesis of the antiasthmatic drug montelukast (Singulair), a silyl ether protecting... Problem 11.48P Problem 11.37P: Following are the steps in the industrial synthesis of glycerin. Provide structures for all...
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Propose single-step and multistep syntheses of ketones and aldehydes from compounds containing otherfunctional groups .
Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.
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