Propanal (CH3CH½CHO) is used in the pharmaceutical industry to make essential ingredients, organic chemicals, industrial chemicals, pesticides, and fertilizers. One of the process routes to produce propanal is via the oxo process by hydroformylation of ethylene using carbon monoxide and hydrogen in the presence of rhodium complex catalyst, according to the following reaction: H,C=CH, + CO + H, → CH,CH,CH=O It has been reported that ethylene hydroformylation occurs with a high propanal selectivity, up to 99% (Gorbunov et al., 2019). The reversible adsorption of the reactants onto the catalyst surface occurs molecularly, and the reaction kinetics is said to be limited by the irreversible surface reaction. (a) Determine a rate expression for the overall reaction.

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Propanal (CH3CH½CHO) is used in the pharmaceutical industry to make essential ingredients,
organic chemicals, industrial chemicals, pesticides, and fertilizers. One of the process routes to
produce propanal is via the oxo process by hydroformylation of ethylene using carbon monoxide
and hydrogen in the presence of rhodium complex catalyst, according to the following reaction:
H,C=CH, + CO + Hz → CH,CH,CH=O
It has been reported that ethylene hydroformylation occurs with a high propanal selectivity, up to
99% (Gorbunov et al., 2019). The reversible adsorption of the reactants onto the catalyst surface
occurs molecularly, and the reaction kinetics is said to be limited by the irreversible surface
reaction.
(a) Determine a rate expression for the overall reaction.
Transcribed Image Text:Propanal (CH3CH½CHO) is used in the pharmaceutical industry to make essential ingredients, organic chemicals, industrial chemicals, pesticides, and fertilizers. One of the process routes to produce propanal is via the oxo process by hydroformylation of ethylene using carbon monoxide and hydrogen in the presence of rhodium complex catalyst, according to the following reaction: H,C=CH, + CO + Hz → CH,CH,CH=O It has been reported that ethylene hydroformylation occurs with a high propanal selectivity, up to 99% (Gorbunov et al., 2019). The reversible adsorption of the reactants onto the catalyst surface occurs molecularly, and the reaction kinetics is said to be limited by the irreversible surface reaction. (a) Determine a rate expression for the overall reaction.
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