processes would ΔS° be expected to be most positive?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1.

For which of the following processes would ΔS° be expected to be most positive?
Group of answer choices
A. H2O(l) → H2O(s)
B. 2NO2(g) → N2O4(g)
C. NH3(g) + HCl(g) → NH4Cl(s)
D.O2(g) + 2H2(g) → 2H2O(g)
E. 2N2H4(g) → 2NH3(g) + N2(g) + H2(g)
F. O2(g) + 2H2(g) → 2H2O(g)
 
2.
For the process HX(s) → HX(l), ΔH° = 9.17 kJ/mol and ΔS° = 43.9 J/mol/K. What is the melting point of HX?
ΔΔ G = ΔΔ H - T ΔΔ S
Group of answer choices
A. –130 °C
B. 130 °C
C. 209 °C
D. 64 °C
E. –64 °C
 
3.
Substance X has a heat of vaporization of 45.1 kJ/mol at its normal boiling point (423°C). For the process X(l) → X(g) at 1 atm and 423°C calculate the value of ΔSsurr.
ΔΔSsurroundings = -ΔΔHsystem/T
Group of answer choices
A. –64.8 J/K mol
B. –107 J/K mol
C. 0
D. 107 J/K mol
E. 64.8 J/K mol
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