Procedure (1) Show the reaction between 4-nitrobenzoic acd and sodium hydroxide. (ChemDraw the structures, and paste below) (2) Give the density of diethyl ether (simply called "ether") in g/mL: (3) Give the density of water in g/mL: (4) Will the density of 5% aqueous NaOH be greater than, less than or the same as that of pure water? (5) For a mixture of 20 mL diethyl ether and 20 mL of aqueous 5% sodium hydroxide, two layers form. Based on densities, which layer is on the bottom? (6) For ether/neutral water, which layer would 4-nitrobenzoic acid be in mainly? (7) For ether/neutral water, which layer would sodium 4-nitrobenzoate be in mainly? (8) For ether/neutral water, which layer would 4-nitrotoluene be in mainly? (9) How is the 4-nitrobenzoic acid isolated from the basic water solution? (give brief outline)
Procedure (1) Show the reaction between 4-nitrobenzoic acd and sodium hydroxide. (ChemDraw the structures, and paste below) (2) Give the density of diethyl ether (simply called "ether") in g/mL: (3) Give the density of water in g/mL: (4) Will the density of 5% aqueous NaOH be greater than, less than or the same as that of pure water? (5) For a mixture of 20 mL diethyl ether and 20 mL of aqueous 5% sodium hydroxide, two layers form. Based on densities, which layer is on the bottom? (6) For ether/neutral water, which layer would 4-nitrobenzoic acid be in mainly? (7) For ether/neutral water, which layer would sodium 4-nitrobenzoate be in mainly? (8) For ether/neutral water, which layer would 4-nitrotoluene be in mainly? (9) How is the 4-nitrobenzoic acid isolated from the basic water solution? (give brief outline)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
![Procedure
(1) Show the reaction between 4-nitrobenzoic acd and sodium hydroxide. (ChemDraw the
structures, and paste below)
(2) Give the density of diethyl ether (simply called "ether") in g/mL:
(3) Give the density of water in g/mL:
(4) Will the density of 5% aqueous NaOH be greater than, less than or the same as that of pure
water?
(5) For a mixture of 20 mL diethyl ether and 20 mL of aqueous 5% sodium hydroxide, two layers
form. Based on densities, which layer is on the bottom?
(6) For ether/neutral water, which layer would 4-nitrobenzoic acid be in mainly?
(7) For ether/neutral water, which layer would sodium 4-nitrobenzoate be in mainly?
(8) For ether/neutral water, which layer would 4-nitrotoluene be in mainly?
(9) How is the 4-nitrobenzoic acid isolated from the basic water solution? (give brief outline)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F29cff20c-e89a-4f61-bb6b-052ee3de92ae%2F08ffde05-4637-44c5-8d0f-9d43b82f9f29%2F0hfd4ls_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Procedure
(1) Show the reaction between 4-nitrobenzoic acd and sodium hydroxide. (ChemDraw the
structures, and paste below)
(2) Give the density of diethyl ether (simply called "ether") in g/mL:
(3) Give the density of water in g/mL:
(4) Will the density of 5% aqueous NaOH be greater than, less than or the same as that of pure
water?
(5) For a mixture of 20 mL diethyl ether and 20 mL of aqueous 5% sodium hydroxide, two layers
form. Based on densities, which layer is on the bottom?
(6) For ether/neutral water, which layer would 4-nitrobenzoic acid be in mainly?
(7) For ether/neutral water, which layer would sodium 4-nitrobenzoate be in mainly?
(8) For ether/neutral water, which layer would 4-nitrotoluene be in mainly?
(9) How is the 4-nitrobenzoic acid isolated from the basic water solution? (give brief outline)
![Water
0.0
100.0
L.000
76.5
SIlica Gel (surface)
Glycerol
2,2,3,3,-Tetra-
fluoropropano1-1
Formamide
1,2-Ethanediol
--
18.2
290
1.26
42.5
106.6
--
1.
2.5
210
1.13
3.4
109.5
-13.0
198
1.11
2.0
37.7
Methanol
-97.8
65.0
791
2.87
32.6
1,3-Propanedlol
N-Methy1formamide
1,2-Propanedlol
Diethylene Glycol
Triethylene Glycol
2-Methoxyethanol
N-Methylacetamide
-26.7
214.4
1.05
2.5
35.0
-3.8
180.5
1.015
3.8
182.4
-60
187.6
1.04
2.25
32.0
-10.5
245.0
1.12
2.3
29.5
-5.
287.4
1.12
3.0
23.7
-85.1
124.5
965
2.1
15.9
29.7
202.4
950
4.3
175.7
Ethanol
-117.
78.3
.789
1.7
24.3
2-Aminoethanol
10.5
171.
1.0215
2.27
37.7
Acetic Acid
16.6
118.5
1.05
1-1.5
6.2
Benzyl Alcohol
1-Propanol
1-Butanol
-15.3
205.3
1.04
1.7
13.1
2.525
3.385
2.8615
-127.
97.4
804
1.7
89.8
117.5
.810
1.7
2-Propanol
2-Butanol
-89.5
82.4
.786
1.7
114.7
99.6
807
4.21
3-Methy1-1,3-dioxol-2-one
(propylene Carbonate)
4-Methy1-1,3-dioxol-2one
(Propylone Carbonate)
132.
810
4.815
1.7
117.2
-48.8
241.7
5.0
2-Pentanol
119.
.809
5.1310
1.66
101.1
81.6
Nitromethane
-28.5
1.14
.647
3.1
Acetonitrile
-43.8
.782
.37515
3.5
7.345
2.005
3-Pentanol
115.3
.820
1.64
1.10
Dimethylsulfoxide
Aniline
18.5
189.0
3.9
-6
184.4
1.02
4.4
1.55
.776
1.26%
3.320
t-Butyl alcohol
Tetramethylenesulfone
25.8
82.5
1.7
28.4
283.
10.3
4.8
"Sulfolane"
A Acetic anhydride
Dimethylformamide
Dimethylacetamide
Propionitrile
Phenylacetonitrile
Acetone
-73.
140.
109"
9715
2.82
-61
153.
.949
.924
3.8
-20
165.5
.937
2.14
3.8
-93.
97.4
.782
454
3.6
-23.8
233.5
1.02
2.16
3.47
-95.3
56.2
.790
3375
2.7
Cyclopropylmethyl Ketone
1-Methyl-2-pyrrolidone
Nitrobenzene
111
1.67
2.1675
-16.
204.
1.03
4.1
5.7
210.8
1.21
4.0](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F29cff20c-e89a-4f61-bb6b-052ee3de92ae%2F08ffde05-4637-44c5-8d0f-9d43b82f9f29%2Fmbhsz9_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Water
0.0
100.0
L.000
76.5
SIlica Gel (surface)
Glycerol
2,2,3,3,-Tetra-
fluoropropano1-1
Formamide
1,2-Ethanediol
--
18.2
290
1.26
42.5
106.6
--
1.
2.5
210
1.13
3.4
109.5
-13.0
198
1.11
2.0
37.7
Methanol
-97.8
65.0
791
2.87
32.6
1,3-Propanedlol
N-Methy1formamide
1,2-Propanedlol
Diethylene Glycol
Triethylene Glycol
2-Methoxyethanol
N-Methylacetamide
-26.7
214.4
1.05
2.5
35.0
-3.8
180.5
1.015
3.8
182.4
-60
187.6
1.04
2.25
32.0
-10.5
245.0
1.12
2.3
29.5
-5.
287.4
1.12
3.0
23.7
-85.1
124.5
965
2.1
15.9
29.7
202.4
950
4.3
175.7
Ethanol
-117.
78.3
.789
1.7
24.3
2-Aminoethanol
10.5
171.
1.0215
2.27
37.7
Acetic Acid
16.6
118.5
1.05
1-1.5
6.2
Benzyl Alcohol
1-Propanol
1-Butanol
-15.3
205.3
1.04
1.7
13.1
2.525
3.385
2.8615
-127.
97.4
804
1.7
89.8
117.5
.810
1.7
2-Propanol
2-Butanol
-89.5
82.4
.786
1.7
114.7
99.6
807
4.21
3-Methy1-1,3-dioxol-2-one
(propylene Carbonate)
4-Methy1-1,3-dioxol-2one
(Propylone Carbonate)
132.
810
4.815
1.7
117.2
-48.8
241.7
5.0
2-Pentanol
119.
.809
5.1310
1.66
101.1
81.6
Nitromethane
-28.5
1.14
.647
3.1
Acetonitrile
-43.8
.782
.37515
3.5
7.345
2.005
3-Pentanol
115.3
.820
1.64
1.10
Dimethylsulfoxide
Aniline
18.5
189.0
3.9
-6
184.4
1.02
4.4
1.55
.776
1.26%
3.320
t-Butyl alcohol
Tetramethylenesulfone
25.8
82.5
1.7
28.4
283.
10.3
4.8
"Sulfolane"
A Acetic anhydride
Dimethylformamide
Dimethylacetamide
Propionitrile
Phenylacetonitrile
Acetone
-73.
140.
109"
9715
2.82
-61
153.
.949
.924
3.8
-20
165.5
.937
2.14
3.8
-93.
97.4
.782
454
3.6
-23.8
233.5
1.02
2.16
3.47
-95.3
56.2
.790
3375
2.7
Cyclopropylmethyl Ketone
1-Methyl-2-pyrrolidone
Nitrobenzene
111
1.67
2.1675
-16.
204.
1.03
4.1
5.7
210.8
1.21
4.0
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