Problem 2.21 Suppose a free particle, which is initially localized in the range -a < x < a, is released at time t = 0: A, if -a < x < a, V (x, 0) = 0, otherwise, where A and a are positive real constants. p. 2 The Time-Independent Schrödinger Equation (a) Determine A, by normalizing V. (b) Determine ø(k) (Equation 2.86). (c) Comment on the behavior of o(k) for very small and very large values of a. How does this relate to the uncertainty principle?
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- Question 6 (Spherical symmetric potential) In quantum mechanics we know that when a spherical symmetric potential V(x,y,z) = V(r) acts on a particle is angular momentum operator L² commutes with the Hamiltonian p² L² H = +V(r): h² 1 d 2m r² ər ²2). + + V(r) 2m 2mr² Note that since the angular dependence is found only in the L², we can separate variables in the wave function. Consider a particle in a spherical and infinite potential well: V(r) = { for So for 0 ≤rsa r>a a) Write the differential equation of the radial part. b) Compute the energy levels and the stationary wave function for l = 0 (Use change of variable such that U(r)=rR(r)).How to get the solutionConsider a particle in a one-dimensional rigid box of length a. Recall that a rigid box has U (x) = 00 for x a, and U () = 0 for 0 )
- Consider a particle of mass, m, with energy, E, moving to the right from -o. This particle is subject to the potential energy V(x) = }V, for 0 V. x z a Sketch a picture that shows the potential energy. In this picture represent a particle moving to the right when x < 0. Solve the time independent Schrodinger equation to find g (x) on the domain -coProblem 1. A free particle has the initial wave function W (.r, 0) = Ae-r where A and a are constants (a is real and positive). (a) Normalize (.x. 0). (b) Find (x,1). (c) Find |(x, t)|².that de/dx = 0 (x). **Problem 2.25 Check the uncertainty principle for the wave function in Equation 2.129. Hint: Calculating (p2) is tricky, because the derivative of has a step discontinuity at x = 0. Use the result in Problem 2.24(b). Partial answer: (p²) = (ma/h)².Solve the time-independent Schrödinger equation with appropriate boundary conditions for an infinite square well centered at the origin [V (x) = 0, for -a/2 < x < +a/2; V (x) = 00 otherwise]. Check that your allowed energies are consistent with mine (Equation 2.23), and confirm that your y's can be obtained from mine (Equation 2.24) by the substitution x x - a/2.B4The wave function of a particle in two dimensions in plane polar coordinates is given by: T ¥(r,0) = A. r. sin0exp[- where A and ao are positive real constants. 1. Find the constant A A using the normalization condition in the form SS |¥(r,0)|²rdrd0 = 1 2. Calculate the expectation values of r, and ². 3. Assuming that the momentum operator in plane polar coordinate is giving in the form ħa p = calculate the expectation values of p and p². 1 Ər' 4. Find the standard deviations of r and p and show that their product is consistent with the Heisenberg uncertainty principle.Subject is physical chemistry. Normalize the two functions and show they are orthogonal.1 The wavefunction of a particle at t = 0 is given by v (0)) = U4)+|u2)], where |u,) and |u,) and u2) are the normalized eigenstates with eigenvahues E, and E, respectively, (E, > E,). The shortest time after which y (t)) will become orthogonal to y (0)) is 2hn (a) (E, – E,) (b) (E, – E,) (c) (E, - E,) (d) (E, - E,)2. Determine the transmission coefficient for a rectangular barrier (same as [Grf] Equation 2.148, only with V(x) = +Vo > 0 in the region -a Vo (note that the wave function inside the barrier is different in three cases). Partial answer: for E< Vo₂ T¹=1+ V2 4E(V₁ - E) 2a ħ sinh? √2m(Vo - E) (5)SEE MORE QUESTIONS