Homework Help is Here – Start Your Trial Now!
Science
Chemistry
Problem 2: Show the fragmentations for4-methyl-2-pentanone radicael carbocation and explain why thatis themost favorable path.Predict ä mass spec for the struicture, ? R CH3

Problem 2: Show the fragmentations for4-methyl-2-pentanone radicael carbocation and explain why thatis themost favorable path.Predict ä mass spec for the struicture, ? R CH3

Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter8: Addition Via Carbocation
Section: Chapter Questions
Problem 6E
See similar textbooks
icon
Related questions
Question

I need help with the mass spec problome 

I linked a sampe example of how the queshtion needs to be answered 

 
Example 1: show the mostfauara ble fragrentation for 2-methylpentane rodical carbocation. * 86 CH3 mass 15 CH3 it CHSCH2CH2 CH{CH3 CH3CH2 CH2¢ • cH3 methyl rodical 2° Carbocation 2- methyipentane rodical carbocetion mass 43 CHs 블 43 + CHCH3 2° carbocadtion primany radicaul This tragmentation is more favorable because a primany radical is more stable than a methyI radical. when answer such questians, it is best to look at tuwo possible frogmentation paths to analyze &compare the types of radicals carbocations that are produced, Always go with the path that offers a more steeble carbocation andlor radičal. For this example, since both produced 2° carbocation, the focus was on the types of radicals is what it would (0ok like: 431 base peak Thighe'st) Relative Alaundance so 100 (m/z) Becouse the charge on the ion is typically tl, the m/z value for a molecular ion comesponds to He moleččular weight of the compounrd. *Remember that the detector Keeps frack of the number of charded particles and translates them into relative abundance. TThe uncharged particles will not appear.
Transcribed Image Text:Example 1: show the mostfauara ble fragrentation for 2-methylpentane rodical carbocation. * 86 CH3 mass 15 CH3 it CHSCH2CH2 CH{CH3 CH3CH2 CH2¢ • cH3 methyl rodical 2° Carbocation 2- methyipentane rodical carbocetion mass 43 CHs 블 43 + CHCH3 2° carbocadtion primany radicaul This tragmentation is more favorable because a primany radical is more stable than a methyI radical. when answer such questians, it is best to look at tuwo possible frogmentation paths to analyze &compare the types of radicals carbocations that are produced, Always go with the path that offers a more steeble carbocation andlor radičal. For this example, since both produced 2° carbocation, the focus was on the types of radicals is what it would (0ok like: 431 base peak Thighe'st) Relative Alaundance so 100 (m/z) Becouse the charge on the ion is typically tl, the m/z value for a molecular ion comesponds to He moleččular weight of the compounrd. *Remember that the detector Keeps frack of the number of charded particles and translates them into relative abundance. TThe uncharged particles will not appear.
Problem 2: Show the froagmentations for 4-methyl-2-pentanone radlcal canoocati on and explain why that is the most favorable path.Predicta mass spec for the stricture. "로 100 ?9? CH3
Transcribed Image Text:Problem 2: Show the froagmentations for 4-methyl-2-pentanone radlcal canoocati on and explain why that is the most favorable path.Predicta mass spec for the stricture. "로 100 ?9? CH3
Expert Solution
steps

Step by step

Solved in 2 steps with 2 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Knowledge Booster
Alkenes
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:
9780618974122
Author:
Andrei Straumanis
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9781305080485
Author:
John E. McMurry
Publisher:
Cengage Learning
Chemistry: Matter and Change
Chemistry: Matter and Change
Chemistry
ISBN:
9780078746376
Author:
Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:
Glencoe/McGraw-Hill School Pub Co
SEE MORE TEXTBOOKS