Problem 1 work done by changes in volume, but our initial framework presented accommodates other forms of work as well. When a ligament is stretched, we may represent the work done on the system as follows: Suppose we're interested in studying ligaments. In class, we have focused on dw = fdl – pdV Here, fis the restoring force of the ligament that opposes stretching, and /is the length. The differential expression for the Gibb's free energy can be written as follows: dG = Vdp – SdT + fdl a) Write all Maxwell relations from the Gibb's free energy differential expression. b) Derive the differential expression for Helmholtz free energy, dA.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Suppose we're interested in studying ligaments. In class, we have focused on
Problem 1
work done by changes in volume, but our initial framework presented accommodates other forms of
work as well. When a ligament is stretched, we may represent the work done on the system as
follows:
dw
fdl - pdV
||
Here, fis the restoring force of the ligament that opposes stretching, and /is the length.
The differential expression for the Gibb's free energy can be written as follows:
dG
= Vdp – SdT + fdl
differential expression.
dA.
a) Write all Maxwell relations from the Gibb's free
energy
energy,
b) Derive the differential expression for Helmholtz free
Transcribed Image Text:Suppose we're interested in studying ligaments. In class, we have focused on Problem 1 work done by changes in volume, but our initial framework presented accommodates other forms of work as well. When a ligament is stretched, we may represent the work done on the system as follows: dw fdl - pdV || Here, fis the restoring force of the ligament that opposes stretching, and /is the length. The differential expression for the Gibb's free energy can be written as follows: dG = Vdp – SdT + fdl differential expression. dA. a) Write all Maxwell relations from the Gibb's free energy energy, b) Derive the differential expression for Helmholtz free
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