Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

Transcribed Image Text:Consider the following
mechanism for the
oxidation of bromide
ions by hydrogen
peroxide in aqueous
acid solution.
Elementary Step 1
H* + H₂O₂ = {H₂O*-
OH) (rapid
equilibrium)
Elementary Step 2
(H₂O*-OH) + Br¯ →
HOBr + H₂O (slowest)
Elementary Step 3
HOBr + H+ + Br¯ → Br₂ +
H₂O (fast)
Consider the reaction
profile below. What is
the approximate
potential energy for the
activated complex (AC)
of elementary step 1?

Transcribed Image Text:Potential Energy (kJ/mol)
Potential Energy (kJ/mol)
Reacton Profile
360
280
160
140
100
60
0
Reaction Progress
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