Potassium nitrate, KNO,, has a molar mass of 101.1 g/mol. In a constant-pressure calorimeter, 36.9 g of KNO, is dissolved in 283 g of water at 23.00 °C. KNO,(s) H,O K*(aq) + NO, (aq) The temperature of the resulting solution decreases to 19.30 °C. Assume that the resulting solution has the same specific heat as water, 4.184 J/(g · °C), and that there is negligible heat loss to the surroundings. How much heat was released by the solution?
Potassium nitrate, KNO,, has a molar mass of 101.1 g/mol. In a constant-pressure calorimeter, 36.9 g of KNO, is dissolved in 283 g of water at 23.00 °C. KNO,(s) H,O K*(aq) + NO, (aq) The temperature of the resulting solution decreases to 19.30 °C. Assume that the resulting solution has the same specific heat as water, 4.184 J/(g · °C), and that there is negligible heat loss to the surroundings. How much heat was released by the solution?
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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![**Title: Calorimetry Experiment with Potassium Nitrate Dissolution**
**Introduction:**
In this experiment, we explore the dissolution of potassium nitrate (KNO₃) in water using a constant-pressure calorimeter. The aim is to determine the heat released during the process and subsequently calculate the enthalpy change of the reaction.
**Experimental Procedure:**
- **Substance:** Potassium nitrate, KNO₃
- **Molar Mass of KNO₃:** 101.1 g/mol
- **Initial Mass of KNO₃:** 36.9 g
- **Water Mass:** 283 g
- **Initial Temperature of Water:** 23.00 °C
**Chemical Reaction:**
\[ \text{KNO}_3(s) \xrightarrow{\text{H}_2\text{O}} \text{K}^+(aq) + \text{NO}_3^-(aq) \]
**Observations:**
The temperature of the solution decreases to 19.30 °C upon dissolution.
**Assumptions:**
- The specific heat capacity of the resulting solution is the same as that of water: 4.184 J/(g·°C).
- Negligible heat loss to the surroundings occurs.
**Calculations:**
1. **Calculation of Heat Released:**
\[
q_{\text{soln}} = \text{[Provide calculation space]} \, \text{kJ}
\]
2. **Determination of Enthalpy Change:**
\[
\Delta H_{\text{rxn}} = \text{[Provide calculation space]} \, \text{kJ/mol}
\]
This guide will allow you to calculate the heat released by the solution and the enthalpy change for the dissolution of KNO₃, using the given mass and temperature data.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F245e0eb4-5097-4578-8f56-633b47cf5980%2F5286725f-8b67-47b1-8180-cd41be45f47e%2F8js7za_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Title: Calorimetry Experiment with Potassium Nitrate Dissolution**
**Introduction:**
In this experiment, we explore the dissolution of potassium nitrate (KNO₃) in water using a constant-pressure calorimeter. The aim is to determine the heat released during the process and subsequently calculate the enthalpy change of the reaction.
**Experimental Procedure:**
- **Substance:** Potassium nitrate, KNO₃
- **Molar Mass of KNO₃:** 101.1 g/mol
- **Initial Mass of KNO₃:** 36.9 g
- **Water Mass:** 283 g
- **Initial Temperature of Water:** 23.00 °C
**Chemical Reaction:**
\[ \text{KNO}_3(s) \xrightarrow{\text{H}_2\text{O}} \text{K}^+(aq) + \text{NO}_3^-(aq) \]
**Observations:**
The temperature of the solution decreases to 19.30 °C upon dissolution.
**Assumptions:**
- The specific heat capacity of the resulting solution is the same as that of water: 4.184 J/(g·°C).
- Negligible heat loss to the surroundings occurs.
**Calculations:**
1. **Calculation of Heat Released:**
\[
q_{\text{soln}} = \text{[Provide calculation space]} \, \text{kJ}
\]
2. **Determination of Enthalpy Change:**
\[
\Delta H_{\text{rxn}} = \text{[Provide calculation space]} \, \text{kJ/mol}
\]
This guide will allow you to calculate the heat released by the solution and the enthalpy change for the dissolution of KNO₃, using the given mass and temperature data.
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