Potassium dichromate (K2Cr2O7) and potassium permanganate (KMnO4) give overlapping UV-Vis absorption spectra in 1 M sulphuric acid. K2Cr2O7 shows an absorption maximum at 440 nm and KMnO4 shows the absorption maximum at 545 nm . An unknown sample solution containing a mixture of K2Cr2O7 and KMnO4 was analyzed using a 1-cm cell and the absorbance values at these two wavelengths were as follows: A440 = 0.515 and A545 = 0.835 The absorbance values for standard solutions of K2Cr2O7 (1.00 x 10-3 M) and KMnO4 (2.00 x 10-4 M) in 1 M sulphuric acid using the same 1 cm cell were as follows: Calculate the concentrations of K2Cr2O7 and KMnO4 in the unknown sample.
Potassium dichromate (K2Cr2O7) and potassium permanganate (KMnO4) give overlapping UV-Vis absorption spectra in 1 M sulphuric acid. K2Cr2O7 shows an absorption maximum at 440 nm and KMnO4 shows the absorption maximum at 545 nm . An unknown sample solution containing a mixture of K2Cr2O7 and KMnO4 was analyzed using a 1-cm cell and the absorbance values at these two wavelengths were as follows: A440 = 0.515 and A545 = 0.835 The absorbance values for standard solutions of K2Cr2O7 (1.00 x 10-3 M) and KMnO4 (2.00 x 10-4 M) in 1 M sulphuric acid using the same 1 cm cell were as follows: Calculate the concentrations of K2Cr2O7 and KMnO4 in the unknown sample.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Potassium dichromate (K2Cr2O7) and potassium permanganate (KMnO4) give overlapping UV-Vis absorption spectra in 1 M sulphuric acid. K2Cr2O7 shows an absorption maximum at 440 nm and KMnO4 shows the absorption maximum at 545 nm . An unknown sample solution containing a mixture of K2Cr2O7 and KMnO4 was analyzed using a 1-cm cell and the absorbance values at these two wavelengths were as follows:
A440 = 0.515 and A545 = 0.835
The absorbance values for standard solutions of K2Cr2O7 (1.00 x 10-3 M) and KMnO4 (2.00 x 10-4 M) in 1 M sulphuric acid using the same 1 cm cell were as follows:
Calculate the concentrations of K2Cr2O7 and KMnO4 in the unknown sample.
Transcribed Image Text:Absorbance, A
Absorbance, A
440 nm
545 m
KCrO,
0.374
0.009
KMnO
0.019
0.475
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