Please find the Theoretical yield following the oxidation reaction provided below: In a 50 mL round bottom flask dissolve 10 g (10 mmol) of cyclohexanol in 4 mL of ethyl acetate and add a magnetic stirring bar. Add 4g (13 mmol equivalent of KHSO5) to the flask while stirring. Add 0.12 g (2.2 mol) of NaCl followed by 1.5 mL of deionized water. Stir the reaction for 40 minutes at room temperature. Add additional NaCl (0.05 g, 0.7 mmol) and stir for 10 minutes. Add 15 mL of deionized water to dissolve all the salts. Slowly add a spatula tip of solid sodium bisulfite to destroy any excess oxidant. Test the aqueous layer with starch-iodide test paper and add additional sodium bisulfite until this test is negative for oxidant. Extract the product with ethyl acetate (2 X 5 mL), wash with saturated NaCl solution and dry the organic layer over magnesium sulfate.
Please find the Theoretical yield following the oxidation reaction provided below: In a 50 mL round bottom flask dissolve 10 g (10 mmol) of cyclohexanol in 4 mL of ethyl acetate and add a magnetic stirring bar. Add 4g (13 mmol equivalent of KHSO5) to the flask while stirring. Add 0.12 g (2.2 mol) of NaCl followed by 1.5 mL of deionized water. Stir the reaction for 40 minutes at room temperature. Add additional NaCl (0.05 g, 0.7 mmol) and stir for 10 minutes. Add 15 mL of deionized water to dissolve all the salts. Slowly add a spatula tip of solid sodium bisulfite to destroy any excess oxidant. Test the aqueous layer with starch-iodide test paper and add additional sodium bisulfite until this test is negative for oxidant. Extract the product with ethyl acetate (2 X 5 mL), wash with saturated NaCl solution and dry the organic layer over magnesium sulfate.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please find the Theoretical yield following the oxidation reaction provided below:
- In a 50 mL round bottom flask dissolve 10 g (10 mmol) of cyclohexanol in 4 mL of ethyl acetate and add a magnetic stirring bar.
- Add 4g (13 mmol equivalent of KHSO5) to the flask while stirring.
- Add 0.12 g (2.2 mol) of NaCl followed by 1.5 mL of deionized water.
- Stir the reaction for 40 minutes at room temperature.
- Add additional NaCl (0.05 g, 0.7 mmol) and stir for 10 minutes.
- Add 15 mL of deionized water to dissolve all the salts.
- Slowly add a spatula tip of solid sodium bisulfite to destroy any excess oxidant.
- Test the aqueous layer with starch-iodide test paper and add additional sodium bisulfite until this test is negative for oxidant.
- Extract the product with ethyl acetate (2 X 5 mL), wash with saturated NaCl solution and dry the organic layer over magnesium sulfate.
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