pisiod noh 23.40 Consider the following three complexes: (Complex 1) [Co(NH3)5SCN]²+ (Complex 2) [Co(NH3);Cl3]2+ (Complex 3) COCIBR 5NH3 Which of the three complexes can have (a) geometric iso- mers, (b) linkage isomers, (c) optical isomers, (d) coordina- tion-sphere isomers? 41 A four-coordinate complex MA,B2 is prepared and found to have two different isomers. Is it possible to determine from this information whether the complex is square planar or tetrahedral? If so, which is it? 12 Consider an octahedral complex MA3B3. How many geo- metric isomers are expected for this compound? Will any of the isomers be optically active? If so, which ones? 3 Determine if each of the following complexes exhibits geo- metric isomerism. If geometric isomers exist, determine hoW many there are. (a) tetrahedral [Cd(H2O),Cl2], (b) square-pla- nar (IrCl,(PH3)2] , (c) octahedral [Fe(o-phen),Cl2]*. Determine if each of the following complexes exhibits geometric isomerism. If geometric isomers exist, deter- mine how many there are. (a) [Rh(bipy) (o-phen)2]** (b) [Co(NH3)3(bipy)Br]*, (c) square-planar [Pd(en) Determine if each of the following hiral and therefore has an 3+ Zn(H,O),CL,, (h edral

pisiod noh 23.40 Consider the following three complexes: (Complex 1) [Co(NH3)5SCN]²+ (Complex 2) [Co(NH3);Cl3]2+ (Complex 3) COCIBR 5NH3 Which of the three complexes can have (a) geometric iso- mers, (b) linkage isomers, (c) optical isomers, (d) coordina- tion-sphere isomers? 41 A four-coordinate complex MA,B2 is prepared and found to have two different isomers. Is it possible to determine from this information whether the complex is square planar or tetrahedral? If so, which is it? 12 Consider an octahedral complex MA3B3. How many geo- metric isomers are expected for this compound? Will any of the isomers be optically active? If so, which ones? 3 Determine if each of the following complexes exhibits geo- metric isomerism. If geometric isomers exist, determine hoW many there are. (a) tetrahedral [Cd(H2O),Cl2], (b) square-pla- nar (IrCl,(PH3)2] , (c) octahedral [Fe(o-phen),Cl2]*. Determine if each of the following complexes exhibits geometric isomerism. If geometric isomers exist, deter- mine how many there are. (a) [Rh(bipy) (o-phen)2]** (b) [Co(NH3)3(bipy)Br]*, (c) square-planar [Pd(en) Determine if each of the following hiral and therefore has an 3+ Zn(H,O),CL,, (h edral

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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quetion 31
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