Pick the one that BEST applies. There is no reaction. A supersaturated solution is one that: a. is at equilibruim, and has [Na+][acetate] > Ksp. b. is at equilibruim, and has [Na+][acetate] < Ksp. c. is NOT at equilibruim, and has [Na+][acetate] < Ksp. d. is NOT at equilibruim, and has [Na+][acetate] > Ksp.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Pick the one that BEST applies. There is no reaction. A supersaturated solution is one that:

a. is at equilibruim, and has [Na+][acetate] > Ksp.

b. is at equilibruim, and has [Na+][acetate] < Ksp.

c. is NOT at equilibruim, and has [Na+][acetate] < Ksp.

d. is NOT at equilibruim, and has [Na+][acetate] > Ksp.

Expert Solution
Step 1

From the options I can relate that the salt we are taking about is sodium acetate i.e NaCH3COO.

The solubility reaction of NaCH3COO can be written as,

=> NaCH3COO (s) ------> Na+ (aq) + CH3COO- (aq)                               Ksp 

where Ksp = equilibrium constant of the reaction.

Since the solid component's concentration is not written in the equilibrium constant expression.

Hence the equilibrium constant expression for the above reaction can be written as,

=> Ksp = [Na+ ][CH3COO- ]

where [Na+ ] = saturation or equilibrium concentration of Na+ ions and

[CH3COO- ] = saturation or equilibrium concentration of CH3COO- ions.

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